caa a22 4500 467920001 CHVBK 20180406152914.0 cr unu---uuuuu 170328e20060401xx s 000 0 eng 10.1007/s00706-005-0457-x doi (NATIONALLICENCE)springer-10.1007/s00706-005-0457-x Thermodynamic Properties and Melting Behavior of Bi-Sn-Zn Alloys [Elektronische Daten] [Christoph Luef, Aloke Paul, Jiri Vizdal, Ales Kroupa, Alexander Kodentsov, Herbert Ipser] Summary.: The partial and integral enthalpies of mixing of liquid Bi-Sn-Zn alloys were determined at 500°C by a drop calorimetric technique using a Calvet-type microcalorimeter. The ternary interaction parameters in the Bi-Sn-Zn system were fitted using the Redlich-Kister-Muggianu model for substitutional solutions, and isoenthalpy curves of the integral molar enthalpy of mixing at 500°C were constructed. Furthermore, a DSC technique was used to determine the liquidus temperatures in three sections (3, 5, and 7 at.% Zn) as well as the invariant reaction temperature of the ternary eutectic L ⇄ (Bi) + (Sn) + (Zn). The ternary eutectic reaction was found at 135°C. Springer-Verlag/Wien, 2006 Keywords. Alloys nationallicence Calorimetry nationallicence Thermochemistry nationallicence Enthalpy of mixing nationallicence Liquidus temperatures nationallicence Luef Christoph Institut für Anorganische Chemie - Materialchemie, Universität Wien, 1090, Wien, Austria aut Paul Aloke Department of Chemical Engineering and Chemistry, Laboratory of Materials and Interface Chemistry, Eindhoven University of Technology, 5600, MB Eindhoven, The Netherlands aut Vizdal Jiri Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 61662, Brno, Czech Republic aut Kroupa Ales Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 61662, Brno, Czech Republic aut Kodentsov Alexander Department of Chemical Engineering and Chemistry, Laboratory of Materials and Interface Chemistry, Eindhoven University of Technology, 5600, MB Eindhoven, The Netherlands aut Ipser Herbert Institut für Anorganische Chemie - Materialchemie, Universität Wien, 1090, Wien, Austria aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/4(2006-04-01), 381-395 0026-9247 137:4<381 2006 137 706 https://doi.org/10.1007/s00706-005-0457-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s00706-005-0457-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Luef Christoph Institut für Anorganische Chemie - Materialchemie, Universität Wien, 1090, Wien, Austria aut NATIONALLICENCE 700 1- Paul Aloke Department of Chemical Engineering and Chemistry, Laboratory of Materials and Interface Chemistry, Eindhoven University of Technology, 5600, MB Eindhoven, The Netherlands aut NATIONALLICENCE 700 1- Vizdal Jiri Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 61662, Brno, Czech Republic aut NATIONALLICENCE 700 1- Kroupa Ales Institute of Physics of Materials, Academy of Sciences of the Czech Republic, 61662, Brno, Czech Republic aut NATIONALLICENCE 700 1- Kodentsov Alexander Department of Chemical Engineering and Chemistry, Laboratory of Materials and Interface Chemistry, Eindhoven University of Technology, 5600, MB Eindhoven, The Netherlands aut NATIONALLICENCE 700 1- Ipser Herbert Institut für Anorganische Chemie - Materialchemie, Universität Wien, 1090, Wien, Austria aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/4(2006-04-01), 381-395 0026-9247 137:4<381 2006 137 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer