caa a22 4500 467920087 CHVBK 20180406152914.0 cr unu---uuuuu 170328e20060801xx s 000 0 eng 10.1007/s00706-006-0510-4 doi (NATIONALLICENCE)springer-10.1007/s00706-006-0510-4 Si-Containing Amides of Phosphoric Acid [Elektronische Daten] [Vadim A. Pestunovich, Nataliya F. Lazareva, Alexander I. Albanov] Summary.: The first representative of the N-silylmethylamides of phosphoric acid O=P[NMe(CH2SiMe n (OEt)3-n ]3 have been synthesized by interaction of MeNHCH2SiMe n (OEt)3-n (n = 2, 3) with POCl3. The interaction of the N,N′,N″-trimethyl-N,N′,N″-tris[(ethoxydimethyl- silyl)methyl]triamide phosphoric acid with BF3·Et2O or BCl3 results in the formation of the N,N′,N″-trimethyl-N,N′,N″-tris[(fluorodimethyl-silyl)methyl]triamide phosphoric acid or N,N′,N″-trimethyl-N,N′,N″-tris[(chlorodimethylsilyl)methyl]triamide phosphoric acid. NMR data show on the tetracoordinate state of silicon in these products. Springer-Verlag, 2006 Keywords. N -Silylmethylamides nationallicence Phosphoric acid nationallicence Pestunovich Vadim A. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia aut Lazareva Nataliya F. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia aut Albanov Alexander I. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/8(2006-08-01), 1005-1013 0026-9247 137:8<1005 2006 137 706 https://doi.org/10.1007/s00706-006-0510-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s00706-006-0510-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Pestunovich Vadim A. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia aut NATIONALLICENCE 700 1- Lazareva Nataliya F. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia aut NATIONALLICENCE 700 1- Albanov Alexander I. A. E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/8(2006-08-01), 1005-1013 0026-9247 137:8<1005 2006 137 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer