caa a22 4500 467920141 CHVBK 20180406152914.0 cr unu---uuuuu 170328e20060801xx s 000 0 eng 10.1007/s00706-006-0505-1 doi (NATIONALLICENCE)springer-10.1007/s00706-006-0505-1 Crystal Structure and Spectral Characterization of a Rare Example of a Salen-Type Zinc Complex with Neutral Monodentate Oxygen Donor Ligands Coordination [Elektronische Daten] [Małgorzata T. Kaczmarek, Maciej Kubicki, Wanda Radecka-Paryzek] Summary.: The new zinc complex of the N,N′-bis(salicylidene)-4-methyl-1,3-phenylenediamine ligand as a product of the [2 + 1] Schiff base condensation process was synthesized in the one-step metal-promoted reaction between salicylaldehyde and 4-methyl-1,3-phenylenediamine in ethanol in the presence of zinc chloride. The two potentially tetradentate N2O2 Schiff bases function as neutral monodentate ligands involving only one oxygen atom in coordination. This rare coordination pattern of a mononuclear salen-type zinc complex was revealed by X-ray crystallography and correlated with spectroscopic characterization. Springer-Verlag, 2006 Keywords. Crystal structure nationallicence Zinc nationallicence Salicylaldimines nationallicence Schiff base complexes nationallicence O-Salen-type ligand nationallicence Kaczmarek Małgorzata T. Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland aut Kubicki Maciej Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland aut Radecka-Paryzek Wanda Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/8(2006-08-01), 997-1003 0026-9247 137:8<997 2006 137 706 https://doi.org/10.1007/s00706-006-0505-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s00706-006-0505-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kaczmarek Małgorzata T. Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland aut NATIONALLICENCE 700 1- Kubicki Maciej Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland aut NATIONALLICENCE 700 1- Radecka-Paryzek Wanda Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/8(2006-08-01), 997-1003 0026-9247 137:8<997 2006 137 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer