caa a22 4500 467920206 CHVBK 20180406152915.0 cr unu---uuuuu 170328e20060501xx s 000 0 eng 10.1007/s00706-006-0461-9 doi (NATIONALLICENCE)springer-10.1007/s00706-006-0461-9 Modification of (Poly)Siloxanes via Hydrosilylation Catalyzed by Rhodium Complex in Ionic Liquids [Elektronische Daten] [Bogdan Marciniec, Hieronim Maciejewski, Karol Szubert, Magdalena Kurdykowska] Summary.: The hydrosilylation of 1-heptene, allyl glycidyl ether and, allyl polyether by heptamethylhydrotrisiloxane and poly(hydro, methyl)(dimethyl)siloxane catalyzed by rhodium(I) complexes (particularly [{Rh(μ-OSiMe3)(cod)}2]) in imidazolium ionic liquids (especially [TriMIM]MeSO4) gives heptyl and glycidyloxy functional (poly)siloxanes and silicone polyethers with high yield and selectivity. The catalytic system based on rhodium siloxide can be easily separated from the product and successfully reused up to five times. Springer-Verlag, 2006 Keywords. TM complexes nationallicence Catalysis nationallicence (Poly)Siloxanes nationallicence Hydrosilylation nationallicence Ionic liquids nationallicence Marciniec Bogdan Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut Maciejewski Hieronim Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut Szubert Karol Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut Kurdykowska Magdalena Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/5(2006-05-01), 605-611 0026-9247 137:5<605 2006 137 706 https://doi.org/10.1007/s00706-006-0461-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s00706-006-0461-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Marciniec Bogdan Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut NATIONALLICENCE 700 1- Maciejewski Hieronim Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut NATIONALLICENCE 700 1- Szubert Karol Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut NATIONALLICENCE 700 1- Kurdykowska Magdalena Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 137/5(2006-05-01), 605-611 0026-9247 137:5<605 2006 137 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer