caa a22 4500 467923019 CHVBK 20180406152922.0 cr unu---uuuuu 170328e20061201xx s 000 0 eng 10.1134/S1087659606060113 doi (NATIONALLICENCE)springer-10.1134/S1087659606060113 Evolution of the properties of sol-gel derived hybrid organic-inorganic xerogels and coatings in the course of heat treatment [Elektronische Daten] [E. Tarasyuk, O. Shilova, V. Dubok, Yu. Gomza, A. Lapshin, V. Kornilova, L. Kuz'menko] The sol-gel systems and thin-layer insulating coatings prepared from these systems are investigated by a number of modern experimental techniques, such as IR spectroscopy, differential thermal and X-ray powder diffraction analyses, and methods of extraction and reduction of carbon. These coating are successfully used as electrical insulation for winding wires and other metal surfaces. The glass-ceramic coatings on nickel plates are prepared from the sol-gel system based on tetraethoxysilane (TEOS); potassium, strontium, lead, and cobalt nitrates; low-and high-molecular polyols; and a finely dispersed filler Cr2O3. It is revealed that the structure and composition of the prepared silicate and hybrid xerogels and coatings are changed in the course of their heat treatment and upon introduction of organic modifiers (polyols) into the sols. Pleiades Publishing, Inc., 2006 Tarasyuk E. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut Shilova O. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut Dubok V. Frantsevich Institute of Materials Science Problems, National Academy of Sciences of Ukraine, ul. Krzhizhanovskogo 3, 03142, Kiev, Ukraine aut Gomza Yu Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kharkovskoe sh. 48, 02160, Kiev, Ukraine aut Lapshin A. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut Kornilova V. Frantsevich Institute of Materials Science Problems, National Academy of Sciences of Ukraine, ul. Krzhizhanovskogo 3, 03142, Kiev, Ukraine aut Kuz'menko L. Frantsevich Institute of Materials Science Problems, National Academy of Sciences of Ukraine, ul. Krzhizhanovskogo 3, 03142, Kiev, Ukraine aut Glass Physics and Chemistry Nauka/Interperiodica 32/6(2006-12-01), 656-665 1087-6596 32:6<656 2006 32 10720 https://doi.org/10.1134/S1087659606060113 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1134/S1087659606060113 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Tarasyuk E. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Shilova O. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Dubok V. Frantsevich Institute of Materials Science Problems, National Academy of Sciences of Ukraine, ul. Krzhizhanovskogo 3, 03142, Kiev, Ukraine aut NATIONALLICENCE 700 1- Gomza Yu Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kharkovskoe sh. 48, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Lapshin A. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Kornilova V. Frantsevich Institute of Materials Science Problems, National Academy of Sciences of Ukraine, ul. Krzhizhanovskogo 3, 03142, Kiev, Ukraine aut NATIONALLICENCE 700 1- Kuz'menko L. Frantsevich Institute of Materials Science Problems, National Academy of Sciences of Ukraine, ul. Krzhizhanovskogo 3, 03142, Kiev, Ukraine aut NATIONALLICENCE 773 0- Glass Physics and Chemistry Nauka/Interperiodica 32/6(2006-12-01), 656-665 1087-6596 32:6<656 2006 32 10720 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer