caa a22 4500 467923663 CHVBK 20180406152924.0 cr unu---uuuuu 170328e20060301xx s 000 0 eng 10.1134/S1087659606020106 doi (NATIONALLICENCE)springer-10.1134/S1087659606020106 Calculations of the thermodynamic properties of glasses and melts in the Cs2O-B2O3-SiO2 system in the framework of the generalized lattice theory of associated solutions [Elektronische Daten] [E. Plotnikov, V. Stolyarova] The possibility of calculating the thermodynamic properties of glasses and melts in the Cs2O-B2O3-SiO2 system formed by two glass-former oxides and one modifier oxide with the use of the vacancy variant of the generalized lattice theory of associated solutions is demonstrated. A comparison with the experimental thermodynamic functions determined earlier by high-temperature differential mass spectrometry and electromotive force method shows that the calculations performed within this approach lead to reliable thermodynamic functions. The thermodynamic properties and structural features (the relative numbers of bonds with due regard for the second coordination sphere) of glasses and melts in the Cs2O-B2O3-SiO2 system are analyzed in terms of the generalized lattice theory of associated solutions. Pleiades Publishing, Inc., 2006 Plotnikov E. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut Stolyarova V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut Glass Physics and Chemistry Nauka/Interperiodica 32/2(2006-03-01), 181-190 1087-6596 32:2<181 2006 32 10720 https://doi.org/10.1134/S1087659606020106 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1134/S1087659606020106 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Plotnikov E. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Stolyarova V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, 199155, St. Petersburg, Russia aut NATIONALLICENCE 773 0- Glass Physics and Chemistry Nauka/Interperiodica 32/2(2006-03-01), 181-190 1087-6596 32:2<181 2006 32 10720 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 46688284X BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer