caa a22 4500 467927928 CHVBK 20180406152935.0 cr unu---uuuuu 170328e20061101xx s 000 0 eng 10.1134/S002016850611015X doi (NATIONALLICENCE)springer-10.1134/S002016850611015X Preparation of low-temperature graphite fluorides through decomposition of fluorinated-graphite intercalation compounds [Elektronische Daten] [A. Nazarov, V. Makotchenko, V. Fedorov] The decomposition of C x FCl y · zR (R = N2O4, N2O, SO2) fluorinated graphite intercalation compounds at 370-420 K leads to the formation of C x FCl y graphite fluorides with x close to 2 and y close to 0.1. The C x FCl y fluorides are first-stage compounds with an interlayer spacing of 0.60-0.61 nm. According to the synthesis conditions and their structure, these compounds can be classed with low-temperature C2F graphite fluorides. They are stable in air and inert atmospheres up to 720-750 and 750-780 K, respectively, which is comparable to the thermal stability of high-temperature CF and C2F graphite fluorides. Pleiades Publishing, Inc., 2006 Nazarov A. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, 630090, Novosibirsk, Russia aut Makotchenko V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, 630090, Novosibirsk, Russia aut Fedorov V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, 630090, Novosibirsk, Russia aut Inorganic Materials Nauka/Interperiodica 42/11(2006-11-01), 1260-1264 0020-1685 42:11<1260 2006 42 10789 https://doi.org/10.1134/S002016850611015X text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1134/S002016850611015X text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Nazarov A. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Makotchenko V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Fedorov V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Inorganic Materials Nauka/Interperiodica 42/11(2006-11-01), 1260-1264 0020-1685 42:11<1260 2006 42 10789 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer