caa a22 4500 467943354 CHVBK 20180405193734.0 cr unu---uuuuu 170328e20050101xx s 000 0 eng 10.1007/PL00021873 doi (NATIONALLICENCE)springer-10.1007/PL00021873 (NATIONALLICENCE)springer-10.1007/s10789-005-0053-9 Crystal-chemical aspect of formation of CdAs2-ZnAs2 solid solutions [Elektronische Daten] [V. Sanygin, S. Mikhailov, K. Palkina, A. Steblevskii, A. Kvardakov, S. Marenkin] The initial stages of the formation of CdAs2-ZnAs2 solid solutions are analyzed in terms of crystalchemical energetics. Given that the bond enthalpies decrease in the order H (Zn-As)< H (Cd-As)< H (As-As), it is concluded that, most likely, CdAs2-based solid solutions are substitutional and ZnAs2-based solid solutions are interstitial, and that the thermochemical stability of the substitutional solid solutions is higher than that of CdAs2 . The conclusions drawn from crystal-chemical analysis correlate with the reported x-ray diffraction, chemical analysis, resistivity, and Hall data for the solid solutions. MAIK "Nauka/Interperiodica”, 2005 Sanygin V. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Mikhailov S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Palkina K. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Steblevskii A. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Kvardakov A. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Marenkin S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Inorganic Materials Nauka/Interperiodica 41/1(2005-01-01), 3-6 0020-1685 41:1<3 2005 41 10789 https://doi.org/10.1007/PL00021873 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/PL00021873 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sanygin V. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Mikhailov S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Palkina K. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Steblevskii A. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Kvardakov A. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Marenkin S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 773 0- Inorganic Materials Nauka/Interperiodica 41/1(2005-01-01), 3-6 0020-1685 41:1<3 2005 41 10789 NATIONALLICENCE 856 40 https://doi.org/10.1007/s10789-005-0053-9 text/html Onlinezugriff via DOI Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE NATIONALLICENCE NL-springer