caa a22 4500 467944644 CHVBK 20180405193736.0 cr unu---uuuuu 170328e20050201xx s 000 0 eng 10.1007/s10809-005-0054-5 doi (NATIONALLICENCE)springer-10.1007/s10809-005-0054-5 (NATIONALLICENCE)springer-10.1007/PL00021924 Electrochemical sensors for sulfur- and lead-containing gases [Elektronische Daten] [A. Leushina, E. Makhanova] The possibility of using solid-electrolyte transducers with nonstoichiometric electrodes was studied, and the effect of the material and nonstoichiometry of lead monochalkogenides as measurement electrodes on the work of transducers was considered. The reliability of the results obtained was substantiated by comparing the calculated thermodynamic properties of the measurement electrodes with the corresponding reference values. The effect of nonstoichiometry was assessed from coulometric titration curves. It was noticed that the defect type affects the sensitivity of the transducer. The effect of the surface of the measurement electrode on the process of gas analysis was assessed. The applicability region for the transducers under study was indicated. MAIK "Nauka/Interperiodica”, 2005 Leushina A. Vyatka State University, ul. Moskovskaya, 610000, Kirov, Russia aut Makhanova E. Vyatka State University, ul. Moskovskaya, 610000, Kirov, Russia aut Journal of Analytical Chemistry Nauka/Interperiodica 60/2(2005-02-01), 169-173 1061-9348 60:2<169 2005 60 10809 https://doi.org/10.1007/s10809-005-0054-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10809-005-0054-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Leushina A. Vyatka State University, ul. Moskovskaya, 610000, Kirov, Russia aut NATIONALLICENCE 700 1- Makhanova E. Vyatka State University, ul. Moskovskaya, 610000, Kirov, Russia aut NATIONALLICENCE 773 0- Journal of Analytical Chemistry Nauka/Interperiodica 60/2(2005-02-01), 169-173 1061-9348 60:2<169 2005 60 10809 NATIONALLICENCE 856 40 https://doi.org/10.1007/PL00021924 text/html Onlinezugriff via DOI Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE NATIONALLICENCE NL-springer