caa a22 4500 467945276 CHVBK 20180405193736.0 cr unu---uuuuu 170328e20041101xx s 000 0 eng 10.1007/PL00021790 doi (NATIONALLICENCE)springer-10.1007/PL00021790 (NATIONALLICENCE)springer-10.1007/s10593-005-0063-1 Alkylation of 3-cyano-4-methoxymethyl-6-methyl-2(1h)-pyridone by active Halomethylene compounds. The Molecular structure of 3-amino-2-benzoyl-4-methoxymethyl-6-methylfuro[2,3- b ]pyridine [Elektronische Daten] [E. Kaigorodova, V. Vasilin, E. Sidorova, V. Zavodnik, G. Krapivin] The alkylation of 3-cyano-4-methoxymethyl-6-methyl-2(1H)-pyridone by active halomethylene compounds has been studied. It was shown that the reaction of the pyridone with methyl- and ethylchloroacetates and phenacyl and p-bromophenacyl bromides occurs to give N- and O-structural isomers. Only the N-derivatives are separated from the reaction mixture when the pyridone is alkylated with iodoacetamide. It was found that 2-aroylmethyl-3-cyano-4-methoxymethyl-6-methylpyridines cyclize in the presence of KOH to 3-amino-2-aroyl-4-methoxymethyl-6-methylfuro[2,3-b]pyridines. The molecular structure of 3-amino-2-benzoyl-4-methoxymethyl-6-methylfuro[2,3-b]pyridine has been studied using an X-ray analytical method. Springer Science+Business Media, Inc., 2004 2-aroylmethoxy-3-cyanopyridines nationallicence furo[2,3- b ]pyridine nationallicence 3-cyano-2(1H)-pyridones nationallicence alkylation nationallicence molecular structure nationallicence Kaigorodova E. Kuban State Technological University, 350072, Krasnodar, Russia aut Vasilin V. Kuban State Technological University, 350072, Krasnodar, Russia aut Sidorova E. Kuban State Technological University, 350072, Krasnodar, Russia aut Zavodnik V. Kuban State Technological University, 350072, Krasnodar, Russia aut Krapivin G. Kuban State Technological University, 350072, Krasnodar, Russia aut Chemistry of Heterocyclic Compounds Kluwer Academic Publishers-Consultants Bureau 40/11(2004-11-01), 1442-1453 0009-3122 40:11<1442 2004 40 10593 https://doi.org/10.1007/PL00021790 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/PL00021790 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kaigorodova E. Kuban State Technological University, 350072, Krasnodar, Russia aut NATIONALLICENCE 700 1- Vasilin V. Kuban State Technological University, 350072, Krasnodar, Russia aut NATIONALLICENCE 700 1- Sidorova E. Kuban State Technological University, 350072, Krasnodar, Russia aut NATIONALLICENCE 700 1- Zavodnik V. Kuban State Technological University, 350072, Krasnodar, Russia aut NATIONALLICENCE 700 1- Krapivin G. Kuban State Technological University, 350072, Krasnodar, Russia aut NATIONALLICENCE 773 0- Chemistry of Heterocyclic Compounds Kluwer Academic Publishers-Consultants Bureau 40/11(2004-11-01), 1442-1453 0009-3122 40:11<1442 2004 40 10593 NATIONALLICENCE 856 40 https://doi.org/10.1007/s10593-005-0063-1 text/html Onlinezugriff via DOI Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE NATIONALLICENCE NL-springer