caa a22 4500 467947325 CHVBK 20180405193738.0 cr unu---uuuuu 170328e20050101xx s 000 0 eng 10.1007/s11144-005-0206-5 doi (NATIONALLICENCE)springer-10.1007/s11144-005-0206-5 (NATIONALLICENCE)springer-10.1007/s11144-005-0023-x Kinetic studies on the performance of immobilized quaternary ammonium salt catalysts for the addition of carbon dioxide to phenyl glycidyl ether [Elektronische Daten] [Byung-Soo Yu, Eun-Seon Jeong, Kyung-Hoon Kim, Dae-Won Park, Sang-Wook Park, Jae-Wook Lee] Summary: The addition of carbon dioxide to phenyl glycidyl ether (PGE) was investigated in a semi-batch reactor using immobilized quaternary ammonium chloride catalysts. Five different catalysts were prepared with the following supports : (1) soluble poly(ST-co-VBC) [C1], (2) insoluble poly(ST-DVB-VBC) [C2], (3) macroporous poly(ST-DVB-VBC) [C3], (4) poly(ST-co-VBC)-MMT [C4] (5) modified MCM-41 [C5]. The addition of carbon dioxide to PGE can be considered as a pseudo-first order process with respect to the concentration of PGE. The pseudo-first order rate constant for the catalysts decreased in the series C1>C3>C2>C4>C5. The activation energy for C1 to C5 catalysts was 8.6, 20.9, 19.9, 23.9, and 26.8 kJ/mol, respectively. The immobilized catalysts can be reused in least 4 successive runs without any considerable loss of their initial reactivities. Springer-Verlag/Akadémiai Kiadó, 2005 carbon dioxide nationallicence polystyrene nationallicence Phenyl glycidyl ether nationallicence immobilized catalyst nationallicence Yu Byung-Soo Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut Jeong Eun-Seon Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut Kim Kyung-Hoon Department of Chemical Engineering, Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut Park Dae-Won Department of Chemical Engineering, Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut Park Sang-Wook Department of Chemical Engineering/RIIT, Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut Lee Jae-Wook Department of Chemical Engineering, Sogang University, Seoul, Korea aut Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 84/1(2005-01-01), 175-182 0133-1736 84:1<175 2005 84 11144 https://doi.org/10.1007/s11144-005-0206-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-005-0206-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yu Byung-Soo Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut NATIONALLICENCE 700 1- Jeong Eun-Seon Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut NATIONALLICENCE 700 1- Kim Kyung-Hoon Department of Chemical Engineering, Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut NATIONALLICENCE 700 1- Park Dae-Won Department of Chemical Engineering, Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut NATIONALLICENCE 700 1- Park Sang-Wook Department of Chemical Engineering/RIIT, Department of Chemical Engineering, Pusan National University, Pusan 609-735, Korea aut NATIONALLICENCE 700 1- Lee Jae-Wook Department of Chemical Engineering, Sogang University, Seoul, Korea aut NATIONALLICENCE 773 0- Reaction Kinetics and Catalysis Letters Kluwer Academic Publishers 84/1(2005-01-01), 175-182 0133-1736 84:1<175 2005 84 11144 NATIONALLICENCE 856 40 https://doi.org/10.1007/s11144-005-0023-x text/html Onlinezugriff via DOI Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE NATIONALLICENCE NL-springer