caa a22 4500 467947384 CHVBK 20180405193738.0 cr unu---uuuuu 170328e20050101xx s 000 0 eng 10.1007/s11175-005-0048-5 doi (NATIONALLICENCE)springer-10.1007/s11175-005-0048-5 (NATIONALLICENCE)springer-10.1007/PL00022099 Kinetics of the yttrium fluoride electroreduction in chloride melts [Elektronische Daten] [N. Gasviani, Dzh. Dzhaparidze, G. Kipiani, S. Gasviani, L. Abazadze] To establish the effect of the nature of supporting electrolytes KCl; K, Na/Cl; K, Na, Cs/Cl; and K, Na, Ba/Cl on the electrochemical deposition of yttrium from melts, the electroreduction of yttrium fluoride in the said melts is studied by a linear voltammetry method. The discharge of ions Y3+ in all the melts occurs via one stage. The diffusion coefficients, activation energy, product of transfer coefficients and the number of electrons αn α, diffusion layer thickness, diffusion constant, and rate constant of charge transfer are determined. MAIK "Nauka/Interperiodica”, 2005 electrolysis of melts nationallicence kinetic parameters nationallicence linear voltammetry nationallicence activation energy nationallicence thickness of diffusion layer nationallicence yttrium fluoride nationallicence Gasviani N. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut Dzhaparidze Dzh Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut Kipiani G. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut Gasviani S. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut Abazadze L. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut Russian Journal of Electrochemistry Nauka/Interperiodica 41/1(2005-01-01), 44-48 1023-1935 41:1<44 2005 41 11175 https://doi.org/10.1007/s11175-005-0048-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s11175-005-0048-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gasviani N. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut NATIONALLICENCE 700 1- Dzhaparidze Dzh Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut NATIONALLICENCE 700 1- Kipiani G. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut NATIONALLICENCE 700 1- Gasviani S. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut NATIONALLICENCE 700 1- Abazadze L. Agladze Institute of Inorganic Chemistry and Electrochemistry, Academy of Sciences of Georgia, ul. Jikiya 7, 380086, Tbilisi, Georgia aut NATIONALLICENCE 773 0- Russian Journal of Electrochemistry Nauka/Interperiodica 41/1(2005-01-01), 44-48 1023-1935 41:1<44 2005 41 11175 NATIONALLICENCE 856 40 https://doi.org/10.1007/PL00022099 text/html Onlinezugriff via DOI Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE NATIONALLICENCE NL-springer