caa a22 4500 467954801 CHVBK 20180405193746.0 cr unu---uuuuu 170328e20050101xx s 000 0 eng 10.1007/PL00021988 doi (NATIONALLICENCE)springer-10.1007/PL00021988 (NATIONALLICENCE)springer-10.1007/s10975-005-0047-2 Addition of carbon tetrachloride to olefins in the presence of copper complexes with polyfunctional ligands chemically immobilized on the surface of silica [Elektronische Daten] [V. Smirnov, I. Tarkhanova, A. Kokorin, M. Gantman, D. Tsvetkov] Homogeneous and heterogeneous catalysts containing copper complexes with amino alcohols and hydroxy amino acids were synthesized. Heterogenized systems were immobilized on the surface of silica by covalent bonding of the hydroxyl groups of ligands to the silanol groups of silica. The resulting complexes were active in the reactions of CCl4 addition to multiple bonds of olefins. In the case of 1-octene, the activity of heterogeneous catalysts was an extremal function of metal concentration on the surface, whereas a symbatic relationship was observed for a chlorinated olefin (allyl chloride). The above effects were explained by the participation of different copper complexes, in particular, of different nuclearity, in reactions with different olefins. MAIK "Nauka/Interperiodica”, 2005 Smirnov V. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut Tarkhanova I. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut Kokorin A. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut Gantman M. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut Tsvetkov D. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut Kinetics and Catalysis Nauka/Interperiodica 46/1(2005-01-01), 72-76 0023-1584 46:1<72 2005 46 10975 https://doi.org/10.1007/PL00021988 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/PL00021988 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Smirnov V. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut NATIONALLICENCE 700 1- Tarkhanova I. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut NATIONALLICENCE 700 1- Kokorin A. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut NATIONALLICENCE 700 1- Gantman M. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut NATIONALLICENCE 700 1- Tsvetkov D. Department of Chemistry, Moscow State University, 119899, Moscow, Russia aut NATIONALLICENCE 773 0- Kinetics and Catalysis Nauka/Interperiodica 46/1(2005-01-01), 72-76 0023-1584 46:1<72 2005 46 10975 NATIONALLICENCE 856 40 https://doi.org/10.1007/s10975-005-0047-2 text/html Onlinezugriff via DOI Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE NATIONALLICENCE NL-springer