caa a22 4500 467993289 CHVBK 20180323112550.0 cr unu---uuuuu 170328e19900501xx s 000 0 eng 10.1007/BF00487437 doi (NATIONALLICENCE)springer-10.1007/BF00487437 Heteroadamantanes and their derivatives. 12. Synthesis of 1,3,6-triazahomoadamantane — A new heterocyclic system [Elektronische Daten] [A. Kuznetsov, V. Kosmakov, A. Moskovkii] 8-Nitro-1,3,6-triazahomoadamantane was obtained by the condensation of nitromethane with an equimolar mixture of 1,4,6,9-tetraazatricyclo[4.4.1.14.9]dodecane and hexamethylenetetramine. By reducing it with hydrazine hydrate in the presence of Raney nickel, 8-amino-1,3,6-triazahomoadamantane was synthesized. This was converted to 8-bromo-1,3,6-triazahomoadamantane by the action of sodium nitrite in hydrobromic acid. The 1,3,6-triazahomoadamantane was obtained by reduction of the bromo derivative with hydrazine hydrate in the presence of Raney nickel. The structures of the compounds synthesized were confirmed by PMR and mass spectroscopy. Plenum Publishing Corporation, 1990 Kuznetsov A. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119831, Moscow aut Kosmakov V. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119831, Moscow aut Moskovkii A. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119831, Moscow aut Chemistry of Heterocyclic Compounds Kluwer Academic Publishers-Plenum Publishers 26/5(1990-05-01), 578-581 0009-3122 26:5<578 1990 26 10593 https://doi.org/10.1007/BF00487437 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00487437 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kuznetsov A. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119831, Moscow aut NATIONALLICENCE 700 1- Kosmakov V. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119831, Moscow aut NATIONALLICENCE 700 1- Moskovkii A. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119831, Moscow aut NATIONALLICENCE 773 0- Chemistry of Heterocyclic Compounds Kluwer Academic Publishers-Plenum Publishers 26/5(1990-05-01), 578-581 0009-3122 26:5<578 1990 26 10593 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer