caa a22 4500 467995567 CHVBK 20180323112556.0 cr unu---uuuuu 170328e19900101xx s 000 0 eng 10.1007/BF01244295 doi (NATIONALLICENCE)springer-10.1007/BF01244295 Thermodynamic properties of the dissociation of several α-oxooximes [Elektronische Daten] [Alvaro Izquierdo, José Beltrán, Jacinto Guiteras, Mercé Granados] The changes in free energy, enthalpy and entropy for the dissociation of several α-oxooximes (phenylglyoxal aldoxime, glyoxylanilide oxime,N-ethyl-glyoxylanilide oxime and 1-phenyl-1,2-propanedione-2-oxime) have been determined in water-ethanol medium (50% v/v) at 0.5M ionic strength (NaNO3) and 25 °C. The changes in dissociation free energy were calculated from the pK a values determined by glass-electrode potentiometry, and refined by using the programs MINIGLASS and SUPERQUAD. The dissociation enthalpies were determined by direct thermometric titration, and refined by using the programs MINITERM and MULTITERM. Springer-Verlag, 1990 α-oxooximes nationallicence dissociation constants nationallicence dissociation enthalpies nationallicence dissociation entropies nationallicence Izquierdo Alvaro Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut Beltrán José Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut Guiteras Jacinto Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut Granados Mercé Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut Microchimica Acta Springer-Verlag 102/1-3(1990-01-01), 129-135 0026-3672 102:1-3<129 1990 102 604 https://doi.org/10.1007/BF01244295 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01244295 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Izquierdo Alvaro Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut NATIONALLICENCE 700 1- Beltrán José Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut NATIONALLICENCE 700 1- Guiteras Jacinto Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut NATIONALLICENCE 700 1- Granados Mercé Departament de Quimica Analitica, Universität de Barcelona, Diagonal 647, E-08028, Barcelona, Spain aut NATIONALLICENCE 773 0- Microchimica Acta Springer-Verlag 102/1-3(1990-01-01), 129-135 0026-3672 102:1-3<129 1990 102 604 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer