caa a22 4500 469038365 CHVBK 20180323132802.0 cr unu---uuuuu 170328e19920301xx s 000 0 eng 10.1007/BF00810466 doi (NATIONALLICENCE)springer-10.1007/BF00810466 1H-NMR and electrochemical studies on ligated iron(III)perchlorates in acetonitrile- d 3 [Elektronische Daten] [Karl Kirchner, Rudolf Jedlicka, Roland Schmid] 1H-NMR- und elektrochemische Untersuchungen an koordinierten Eisen(III)perchloraten in Acetonitril- d 3 Summary: Half-wave potentials,E 1/2, of Fe(ligand) 6 3+/2+ , as ClO 4 − salt, [ligand=N,N-dimethylformamide (dmf), acetamide (aa), N,N-dimethylacetamide (dma), trimethylphosphate (tmp), dimethylsulfoxide (dmso), and acetonitrile (MeCN) are given. A linear correlation betweenE 1/2 and Gutmann's donor numbers of the ligands, a parameter which expresses quantitatively the Lewis donor properties towards hard acceptors, was found. Ligand replacement on Fe(ligand) 6 3+ in acetonitrile-d 3 was studied by means of1H-NMR spectroscopy at 20°C. An average number of ligands coordinated to Fe3+,n coord, is given.n coord increases with the ligand's donor strength; i.e.tmp<dmf<dmso. Springer-Verlag, 1992 Half-wave potentials nationallicence Iron(III) complexes nationallicence Ligand exchange nationallicence Kirchner Karl Institute of Inorganic Chemistry, Technical University of Vienna, A-1060, Wien, Austria aut Jedlicka Rudolf Institute of Inorganic Chemistry, Technical University of Vienna, A-1060, Wien, Austria aut Schmid Roland Institute of Inorganic Chemistry, Technical University of Vienna, A-1060, Wien, Austria aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/3(1992-03-01), 203-209 0026-9247 123:3<203 1992 123 706 https://doi.org/10.1007/BF00810466 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00810466 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kirchner Karl Institute of Inorganic Chemistry, Technical University of Vienna, A-1060, Wien, Austria aut NATIONALLICENCE 700 1- Jedlicka Rudolf Institute of Inorganic Chemistry, Technical University of Vienna, A-1060, Wien, Austria aut NATIONALLICENCE 700 1- Schmid Roland Institute of Inorganic Chemistry, Technical University of Vienna, A-1060, Wien, Austria aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/3(1992-03-01), 203-209 0026-9247 123:3<203 1992 123 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer