caa a22 4500 469038594 CHVBK 20180323132803.0 cr unu---uuuuu 170328e19920601xx s 000 0 eng 10.1007/BF00816843 doi (NATIONALLICENCE)springer-10.1007/BF00816843 Reactions of peroxyacetyl radicals with reduced sulfur compounds [Elektronische Daten] [Gerassimos Mineshos, Sotirios Glavas, Ulrich Schurath] Reaktionen von Peroxyacetylradikalen mit reduzierten Schwefelverbindungen Summary: The reaction of peroxyacetyl radicals with reduced sulfur compounds was studied at 55°C in N2 at 1 000 mbar total pressure. The radicals were generated in equilibrium with peroxyacetyl nitrate and NO2 in large excess. The pseudo first order decay ofPAN was measured in the absence and presence of several 100 ppm CH3SH, C2H5SH,n-C4H9SH, (CH3)2S, and (CH3S)2. Computer simulations yielded the following rate constants of peroxyacetyl radicals with the above mentioned sulfur compounds: 3.7, 2.8, 13.0, 0.9, and 1.8·10−16 cm3/s, respectively. An electron capturing compound of the thiols with NO2 was observed. Springer-Verlag, 1992 Reactions nationallicence PAN nationallicence Sulfur compounds nationallicence Mineshos Gerassimos Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut Glavas Sotirios Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut Schurath Ulrich Institut für Physikalische Chemie, Universität Bonn, D-W-5300, Bonn, Federal Republic of Germany aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/6-7(1992-06-01), 501-508 0026-9247 123:6-7<501 1992 123 706 https://doi.org/10.1007/BF00816843 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00816843 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mineshos Gerassimos Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut NATIONALLICENCE 700 1- Glavas Sotirios Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut NATIONALLICENCE 700 1- Schurath Ulrich Institut für Physikalische Chemie, Universität Bonn, D-W-5300, Bonn, Federal Republic of Germany aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/6-7(1992-06-01), 501-508 0026-9247 123:6-7<501 1992 123 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer