caa a22 4500 469039043 CHVBK 20180323132804.0 cr unu---uuuuu 170328e19920101xx s 000 0 eng 10.1007/BF01045298 doi (NATIONALLICENCE)springer-10.1007/BF01045298 Thermal decomposition of peroxyacetyl nitrate in the presence of O2, NO2 and NO [Elektronische Daten] [Nikolaos Roumelis, Sotirios Glavas] Die thermische Zersetzung von Peroxyacetylnitrat in Gegenwart von O2, NO2 und NO Summary: The thermal decomposition of purePAN in N2 as well as in the presence of added O2, NO2 and NO was studied at 1 atm pressure. In addition to methyl nitrate, NO2 was a significant N-product of purePAN in N2 thermal decomposition. In the presence of sufficiently large amounts of O2, no methyl nitrate was formed at 333 K, indicating that the homolyticPAN decay to methyl nitrate and carbon dioxide is not occurring. In the presence of NO (in contrast to former studies) methyl nitrite was found to be the major organo-nitrogen compound instead of methyl nitrate. The systemPAN-NO-N2 allowed the determination of the rate constant 3.1 · 10−4s−1 at 298 K for reaction (1):PAN → CH3COO2+NO2, in agreement with prior studies. Computer simulations based on the free radical mechanism starting with reaction (1) fitted very well the experimental results. Springer-Verlag, 1992 PAN nationallicence Thermal decomposition nationallicence O2 nationallicence NO2 nationallicence NO nationallicence Roumelis Nikolaos Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut Glavas Sotirios Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/1-2(1992-01-01), 63-72 0026-9247 123:1-2<63 1992 123 706 https://doi.org/10.1007/BF01045298 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01045298 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Roumelis Nikolaos Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut NATIONALLICENCE 700 1- Glavas Sotirios Department of Chemistry, University of Patras, GR-26110, Patras, Greece aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/1-2(1992-01-01), 63-72 0026-9247 123:1-2<63 1992 123 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer