caa a22 4500 469039116 CHVBK 20180323132805.0 cr unu---uuuuu 170328e19920501xx s 000 0 eng 10.1007/BF00817594 doi (NATIONALLICENCE)springer-10.1007/BF00817594 Complexes of In(III) with tetraphenylimidodiphosphinate ligands [Elektronische Daten] [Raymundo Cea-Olivares, Rubén Toscano, Gabriela Carreón, Jesús Valdés-Martínez] Komplexe von In(III) mit Tetraphenylimidophosphinat-Liganden We report the synthesis and characterization of the inorganic heterocyclic complexes In(OPPh 2NPPh 2O)3 and In(SPPh 2NPPh 2S)3. The structure of the sulfur derivative was determined by X-ray methods. The complex presents a distorted Oh symmetry and it is compared with the Bi(III) analog. The31P-NMR data and the X-ray structural determination suggest that the bulky ligands are responsible for the geometrical features in these complexes and therefore, for the Bi(III) analogs perhaps the lone pair does not play an important role in the structure. Springer-Verlag, 1992 Indium complexes nationallicence Tetraphenylimidodiphosphinates nationallicence Inorganic rings nationallicence Wynne's theory nationallicence Cea-Olivares Raymundo Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut Toscano Rubén Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut Carreón Gabriela Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut Valdés-Martínez Jesús Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/5(1992-05-01), 391-396 0026-9247 123:5<391 1992 123 706 https://doi.org/10.1007/BF00817594 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00817594 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Cea-Olivares Raymundo Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut NATIONALLICENCE 700 1- Toscano Rubén Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut NATIONALLICENCE 700 1- Carreón Gabriela Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut NATIONALLICENCE 700 1- Valdés-Martínez Jesús Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, D. F., México, México aut NATIONALLICENCE 773 0- Monatshefte für Chemie / Chemical Monthly Springer-Verlag 123/5(1992-05-01), 391-396 0026-9247 123:5<391 1992 123 706 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer