caa a22 4500 469059516 CHVBK 20180323132853.0 cr unu---uuuuu 170328e19920701xx s 000 0 eng 10.1007/BF01042783 doi (NATIONALLICENCE)springer-10.1007/BF01042783 Preparation of an intercalation compound of layered titanic acid H2Ti4O9 with methylene blue [Elektronische Daten] [Teruyuki Nakato, Yumiko Iwata, Kuzuyuki Kuroda, Chuzo Kato] Intercalation of methylene blue into layered titanic acid H2Ti4O9 was examined by a guest exchange method using a propylammonium-H x Ti4O9 intercalation compound as the intermediate. Methylene blue cations were arranged in the interlayer space obliquely to the layer surface. The visible spectrum of the intercalation compound suggested that the methylene blue cations were in an associated state in the interlayer space of H2Ti409. The intercalated methylene blue cations underwent a reversible electrochemical redox reaction in the dark, indicating that intercalation compounds of H2Ti4O9 can be applied to a modified electrode. Kluwer Academic Publishers, 1992 Tetratitanate nationallicence methylene blue nationallicence intercalation nationallicence Nakato Teruyuki Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut Iwata Yumiko Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut Kuroda Kuzuyuki Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut Kato Chuzo Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 13/3(1992-07-01), 249-256 0923-0750 13:3<249 1992 13 10847 https://doi.org/10.1007/BF01042783 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01042783 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Nakato Teruyuki Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut NATIONALLICENCE 700 1- Iwata Yumiko Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut NATIONALLICENCE 700 1- Kuroda Kuzuyuki Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut NATIONALLICENCE 700 1- Kato Chuzo Department of Applied Chemistry, Waseda University, Ohkubo-3, 169, Shinjuku-ku, Tokyo, Japan aut NATIONALLICENCE 773 0- Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 13/3(1992-07-01), 249-256 0923-0750 13:3<249 1992 13 10847 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer