caa a22 4500 469060026 CHVBK 20180323132854.0 cr unu---uuuuu 170328e19920901xx s 000 0 eng 10.1007/BF01045984 doi (NATIONALLICENCE)springer-10.1007/BF01045984 A hydrogen bond between a calixarene (as host and its guest: Crystal and molecular structure of the p -t-butyldihomooxacalix[4]arene [Elektronische Daten] Triethylamine (1 : 2) complex/clathrate [C. Bavoux, M. Perrin] The structure of thep-t-butyldihomooxacalix[4]arene triethylamine (1 : 2 complex has been determined by X-ray crystallography. Crystals are monoclinic, space groupCc,a = 22.821(3),b = 15.257(3),c = 16.365(2) Å,β = 97.44(1)°,V = 5650(1) Å3,Z = 4,D calc = 1.03 g cm−3. One triethylamine (Et3N) molecule has one of its ethyl groups pointing inside the cavity of a calixarene molecule; its nitrogen atom is directed exo to this calixarene molecule and is involved in a hydrogen bond with one of the hydroxy groups of a neighbouring calixarene molecule. This scheme leads to columns of alternating host and guest molecules. The other Et3N molecule is in the interhost space. This feature allows us to define the title compound as a complex/clathrate hybrid. Kluwer Academic Publishers, 1992 Inclusion compounds nationallicence calixarene nationallicence crystal structure nationallicence hydrogen bonding nationallicence amines nationallicence Bavoux C. Laboratoire de Cristallographie. Associé au CNRS, ER0060, Université Claude Bernard Lyon I, 43, boulevard du 11 Novembre 1918-69622, Villeurbanne Cedex, France aut Perrin M. Laboratoire de Cristallographie. Associé au CNRS, ER0060, Université Claude Bernard Lyon I, 43, boulevard du 11 Novembre 1918-69622, Villeurbanne Cedex, France aut Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/3-4(1992-09-01), 247-256 0923-0750 14:3-4<247 1992 14 10847 https://doi.org/10.1007/BF01045984 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01045984 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bavoux C. Laboratoire de Cristallographie. Associé au CNRS, ER0060, Université Claude Bernard Lyon I, 43, boulevard du 11 Novembre 1918-69622, Villeurbanne Cedex, France aut NATIONALLICENCE 700 1- Perrin M. Laboratoire de Cristallographie. Associé au CNRS, ER0060, Université Claude Bernard Lyon I, 43, boulevard du 11 Novembre 1918-69622, Villeurbanne Cedex, France aut NATIONALLICENCE 773 0- Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/3-4(1992-09-01), 247-256 0923-0750 14:3-4<247 1992 14 10847 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer