caa a22 4500 469060050 CHVBK 20180323132854.0 cr unu---uuuuu 170328e19920901xx s 000 0 eng 10.1007/BF01041368 doi (NATIONALLICENCE)springer-10.1007/BF01041368 Interlayer inclusion of tetracyanonickelate anion and water molecules: The crystal and molecular structure of [-ZN(en)2-μ-(NC)2-NI-μ -(CN)2-ZN(en) -] n 2 n + · n [NI(CN)4]2− · 3 n H2O [Elektronische Daten] [Juraj Ćernák, Ivan Potočňák, Václav Petříček, Karel Malý] The crystal structure of [Zn(en)2- (NC)2Ni(CN)2 Zn(en)][Ni(CN)4]· 3 H2O consists of infinite positively charged wave-shaped layers of composition [Zn(en)2-(NC)2Ni(CN)2- Zn(en)] n 2n+ with the [Ni(CN)4]2− anions and water molecules included between them. Both Ni atoms exhibit square-planar coordination. The chelate bonded en (=ethylenediamine) and N-bonded cyano ligands around two independent zinc atoms form a deformed tetrahedron and a deformed octahedron, respectively. Yellow needles of the complex belong to the orthorhombic space groupPbcm witha = 6.977(1),b = 25.407(4),c = 14.876(2)Å,Z = 4,D m = 1.74(1) g cm−3 andD c = 1.739 g cm−3. The structure was refined toR = 6.31 %. Kluwer Academic Publishers, 1992 Crystal structure nationallicence disorder nationallicence ethylenediamine nationallicence inclusion complex nationallicence layered structure nationallicence tetracyanonickelate nationallicence twinning crystals nationallicence zinc nationallicence Ćernák Juraj Department of Inorganic Chemistry, P. J. Šafárik University, Moyzesova 11, CS-041 54, Košice, Czechoslovakia aut Potočňák Ivan Department of Inorganic Chemistry, P. J. Šafárik University, Moyzesova 11, CS-041 54, Košice, Czechoslovakia aut Petříček Václav Institute of Physics, Czechoslovak Academy of Sciences, Na Slovance 2, CS-180 40, Praha 8, Czechoslovakia aut Malý Karel Institute of Physics, Czechoslovak Academy of Sciences, Na Slovance 2, CS-180 40, Praha 8, Czechoslovakia aut Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/1(1992-09-01), 73-80 0923-0750 14:1<73 1992 14 10847 https://doi.org/10.1007/BF01041368 text/html Onlinezugriff via DOI 1 review-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01041368 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ćernák Juraj Department of Inorganic Chemistry, P. J. Šafárik University, Moyzesova 11, CS-041 54, Košice, Czechoslovakia aut NATIONALLICENCE 700 1- Potočňák Ivan Department of Inorganic Chemistry, P. J. Šafárik University, Moyzesova 11, CS-041 54, Košice, Czechoslovakia aut NATIONALLICENCE 700 1- Petříček Václav Institute of Physics, Czechoslovak Academy of Sciences, Na Slovance 2, CS-180 40, Praha 8, Czechoslovakia aut NATIONALLICENCE 700 1- Malý Karel Institute of Physics, Czechoslovak Academy of Sciences, Na Slovance 2, CS-180 40, Praha 8, Czechoslovakia aut NATIONALLICENCE 773 0- Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/1(1992-09-01), 73-80 0923-0750 14:1<73 1992 14 10847 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer