caa a22 4500 469060255 CHVBK 20180323132855.0 cr unu---uuuuu 170328e19920601xx s 000 0 eng 10.1007/BF01029660 doi (NATIONALLICENCE)springer-10.1007/BF01029660 Small-ring inclusion hosts. 4. X-ray crystal structures of trans -3,3-Bis(4-methylphenyl)cyclopropane-1,2-dicarboxylic acid and of its inclusion complex with Dimethyl Sulphoxide (1:2) [Elektronische Daten] [Ingeborg Csöregh, Olga Gallardo, Edwin Weber, Manfred Hecker, Andreas Wierig] The crystal structures of the unsolvatedtrans-3,3-bis(4-methylphenyl)cyclopropane-1,2-dicarboxylic acid (1) and of its inclusion compound with dimethyl sulphoxide,1·DMSO (1:2), have been studied by X-ray diffraction. Crystals of1 show triclinic symmetry (P $$\bar I$$ ) withZ = 4 and the unit cell dimensionsa = 7.617(2),b = 15.321(4),c = 15.297(3) Å,α = 109.76(2),β = 103.47(1),γ = 89.87(2)°. FinalR = 0.037 for 3601 reflections collected atT = 153(1) K. Crystals of1·DMSO (1: 2) are monoclinic (P21/n) withZ = 4 and cell dimensionsa = 10.744(1),b = 10.806(1),c = 21.302(2) Å,β = 101.68(1)°. The clathrate structure was refined toR = 0.034 for 1671 reflections obtained atT = 173(1) K. In the unsolvated host compound cyclic pairs of O-H ... bonds, commonly observed in carboxylic acids, couple the carboxylic functions two by two, thus giving rise to endless chains due to the bifunctionality and thetrans position of the acid groups of1. The complex with DMSO as guest, however, consists of distinct hydrogen-bonded 1:2 host-guest associates, held together by weak intermolecular interactions. Kluwer Academic Publishers, 1992 X-ray structure analysis nationallicence cyclopropanedicarboxylic acid host nationallicence dimethyl sulphoxide nationallicence crystalline complex nationallicence hydrogen bonding nationallicence Csöregh Ingeborg Department of Structural Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91, Stockholm, Sweden aut Gallardo Olga Department of Structural Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91, Stockholm, Sweden aut Weber Edwin Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300, Bonn-1, Germany aut Hecker Manfred Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300, Bonn-1, Germany aut Wierig Andreas Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300, Bonn-1, Germany aut Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/2(1992-06-01), 131-140 0923-0750 14:2<131 1992 14 10847 https://doi.org/10.1007/BF01029660 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01029660 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Csöregh Ingeborg Department of Structural Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91, Stockholm, Sweden aut NATIONALLICENCE 700 1- Gallardo Olga Department of Structural Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91, Stockholm, Sweden aut NATIONALLICENCE 700 1- Weber Edwin Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300, Bonn-1, Germany aut NATIONALLICENCE 700 1- Hecker Manfred Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300, Bonn-1, Germany aut NATIONALLICENCE 700 1- Wierig Andreas Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk-Straße 1, D-5300, Bonn-1, Germany aut NATIONALLICENCE 773 0- Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/2(1992-06-01), 131-140 0923-0750 14:2<131 1992 14 10847 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer