caa a22 4500 469060271 CHVBK 20180323132855.0 cr unu---uuuuu 170328e19920601xx s 000 0 eng 10.1007/BF01029657 doi (NATIONALLICENCE)springer-10.1007/BF01029657 Farina Mario Dipartimento di Chimica Organica e Industriale, Università di Milano, via Y enezian 21, I-20133, Milano, Italy aut Phase diagrams of crystalline adducts containing two volatile components [Elektronische Daten] [Mario Farina] The phase relationships in binary systems forming a crystalline addition compound are obtained by means of classical thermodynamic arguments for the case in which both components are volatile. This approach can be applied to inclusion compounds and to other low-stability addition compounds existing only in the solid phase. The results are consistent with those already known for clathrates containing a volatile guest and a non-volatile host, and for symmetric systems, such as racemic compounds. The temperature range in which the adduct undergoes a congruent sublimation depends on the ratio of the vapor pressures of the two components. A relation has been found to exist between the properties of the pure components, the melting behavior and the enthalpy of formation of the adduct. Kluwer Academic Publishers, 1992 Phase diagrams nationallicence solid-liquid equilibria nationallicence solid-vapor equilibria nationallicence congruent and incongruent vaporization of binary adducts nationallicence addition compounds nationallicence clathrates nationallicence inclusion compounds nationallicence Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/2(1992-06-01), 101-111 0923-0750 14:2<101 1992 14 10847 https://doi.org/10.1007/BF01029657 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01029657 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Farina Mario Dipartimento di Chimica Organica e Industriale, Università di Milano, via Y enezian 21, I-20133, Milano, Italy aut NATIONALLICENCE 773 0- Journal of inclusion phenomena and molecular recognition in chemistry Kluwer Academic Publishers 14/2(1992-06-01), 101-111 0923-0750 14:2<101 1992 14 10847 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer