caa a22 4500 469071966 CHVBK 20180323132924.0 cr unu---uuuuu 170328e19920201xx s 000 0 eng 10.1007/BF00671980 doi (NATIONALLICENCE)springer-10.1007/BF00671980 Guest control of diol inclusion host lattices [Elektronische Daten] [Alison Ung, Roger Bishop, Donald Craig, Ian Dance, Marcia Scudder] A survey of the multimolecular inclusion compounds formed bysyn-2,syn-7-dihydroxy-2,7-dimethyltricyclo[4.3.1.13,8]undecane1 and 34 guest molecules shows that two inclusion crystal structures are commonly obtained, namely the helical tubulate inclusion lattice and the ellipsoidal clathrate structure type. Interactions between host and guest are necessarily weak since the host surface is hydrocarbon. Small differences in the guest molecules can tip the balance between alternative inclusion lattices, one of which is chiral. For the first time precise guest locations in the helical tubulate structure have been obtained by X-ray diffraction analysis. Crystal data:1·CCl4: space groupP3 121,a=13.2812(2),c=6.904(1) Å, unit cell contents 3(C13H22O2) + 1.2CCl4,R=0.044;1·BrCH2CH2CH2Br: space groupP3 121,a=13.206(2),c=6.915(2) Å, unit cell contents 3(C13H22O2)+ BrCH2CH2CH2Br,R=0.042;1.0- xylene: space groupP3 121,a=13.380(2),c=6.905(1) Å, unit cell contents 3(C13H22O2) + 1.2 C8H10,R=0.042. Plenum Publishing Corporation, 1992 Ung Alison School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut Bishop Roger School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut Craig Donald School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut Dance Ian School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut Scudder Marcia School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut Structural Chemistry Kluwer Academic Publishers 3/1(1992-02-01), 59-61 1040-0400 3:1<59 1992 3 11224 https://doi.org/10.1007/BF00671980 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00671980 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ung Alison School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut NATIONALLICENCE 700 1- Bishop Roger School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut NATIONALLICENCE 700 1- Craig Donald School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut NATIONALLICENCE 700 1- Dance Ian School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut NATIONALLICENCE 700 1- Scudder Marcia School of Chemistry, University of New South Wales, 2033, Kensington, NSW, Australia aut NATIONALLICENCE 773 0- Structural Chemistry Kluwer Academic Publishers 3/1(1992-02-01), 59-61 1040-0400 3:1<59 1992 3 11224 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer