caa a22 4500 469072172 CHVBK 20180323132924.0 cr unu---uuuuu 170328e19920601xx s 000 0 eng 10.1007/BF00678416 doi (NATIONALLICENCE)springer-10.1007/BF00678416 Crystal and molecular structure of 2-acetyl-5-methyl-3-phenylfuran [Elektronische Daten] [T. Balaban, A. Balaban, D. Daia, K. Turdybekov, S. Lindeman, Yu. Struchkov] The molecular structure of the title compound indicates that it possesses a transoid structure of the O=C-C-O group, and a dihedral angle of about 40° between the furan and phenyl rings. The same conformation is predominant also in CDCl3 solution as indicated by europium chelate induced proton shifts. The corresponding 2,4-dinitrophenyhydrazone has, however, the cisoid isomer stabilized by an intramolecular hydrogen bond. Plenum Publishing Corporation, 1992 Balaban T. Center of Organic Chemistry, Splaiul Independentei 202 B, PO 15-258, 71141, Bucharest, Romania aut Balaban A. Polytechnic Institute, Organic Chemistry Department, Splaiul Independentei 313, 77206, Bucharest, Romania aut Daia D. Polytechnic Institute, Organic Chemistry Department, Splaiul Independentei 313, 77206, Bucharest, Romania aut Turdybekov K. Institute of Elemento-Organic Compounds of the USSR Academy of Sciences, 28 Vavilov Street, 117813, Moscow, USSR aut Lindeman S. Institute of Elemento-Organic Compounds of the USSR Academy of Sciences, 28 Vavilov Street, 117813, Moscow, USSR aut Struchkov Yu Institute of Elemento-Organic Compounds of the USSR Academy of Sciences, 28 Vavilov Street, 117813, Moscow, USSR aut Structural Chemistry Kluwer Academic Publishers 3/3(1992-06-01), 191-194 1040-0400 3:3<191 1992 3 11224 https://doi.org/10.1007/BF00678416 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00678416 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Balaban T. Center of Organic Chemistry, Splaiul Independentei 202 B, PO 15-258, 71141, Bucharest, Romania aut NATIONALLICENCE 700 1- Balaban A. Polytechnic Institute, Organic Chemistry Department, Splaiul Independentei 313, 77206, Bucharest, Romania aut NATIONALLICENCE 700 1- Daia D. Polytechnic Institute, Organic Chemistry Department, Splaiul Independentei 313, 77206, Bucharest, Romania aut NATIONALLICENCE 700 1- Turdybekov K. Institute of Elemento-Organic Compounds of the USSR Academy of Sciences, 28 Vavilov Street, 117813, Moscow, USSR aut NATIONALLICENCE 700 1- Lindeman S. Institute of Elemento-Organic Compounds of the USSR Academy of Sciences, 28 Vavilov Street, 117813, Moscow, USSR aut NATIONALLICENCE 700 1- Struchkov Yu Institute of Elemento-Organic Compounds of the USSR Academy of Sciences, 28 Vavilov Street, 117813, Moscow, USSR aut NATIONALLICENCE 773 0- Structural Chemistry Kluwer Academic Publishers 3/3(1992-06-01), 191-194 1040-0400 3:3<191 1992 3 11224 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer