caa a22 4500 46907227X CHVBK 20180323132925.0 cr unu---uuuuu 170328e19920801xx s 000 0 eng 10.1007/BF00672791 doi (NATIONALLICENCE)springer-10.1007/BF00672791 Contributions to the chemistry of silicon-sulfur compounds. Part 59 [Elektronische Daten] A MO study of the acidity of silanethiols: Comparison with the corresponding carbon compounds [A. Herman, W. Wojnowski] The contribution of vacantπ orbitals of the silicon atom to the electronic structure of silanethiols and their corresponding deprotonated species have been studied by means of ab initio and EHT MO methods. The results have been compared with those of the corresponding carbon compounds to clarify the peculiar properties of the silanethiols. The deprotonation process does strengthen the Si-S bond, but this effect is not considered to be due to the SSi dativeπ bonding as suggested by Salinger and West. Plenum Publishing Corporation, 1992 Herman A. Department of Chemistry, Technical University, 80-952, Gdańsk, Poland aut Wojnowski W. Department of Chemistry, Technical University, 80-952, Gdańsk, Poland aut Structural Chemistry Kluwer Academic Publishers-Plenum Publishers 3/4(1992-08-01), 239-244 1040-0400 3:4<239 1992 3 11224 https://doi.org/10.1007/BF00672791 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00672791 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Herman A. Department of Chemistry, Technical University, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Wojnowski W. Department of Chemistry, Technical University, 80-952, Gdańsk, Poland aut NATIONALLICENCE 773 0- Structural Chemistry Kluwer Academic Publishers-Plenum Publishers 3/4(1992-08-01), 239-244 1040-0400 3:4<239 1992 3 11224 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer