caa a22 4500 469072377 CHVBK 20180323132925.0 cr unu---uuuuu 170328e19921001xx s 000 0 eng 10.1007/BF00678559 doi (NATIONALLICENCE)springer-10.1007/BF00678559 Low temperature crystal and molecular structure of nitrobenzene [Elektronische Daten] [Roland Boese, Dieter Bläser, Michael Nussbaumer, Tadeusz Krygowski] The crystal and molecular structure of nitrobenzene was determined at 103 K by X-ray diffraction, yieldingR=0.034 and a highly precise geometry of the molecule (esds of bond lengths ≤0.001 Å and bond angles ≤0.1°). The bond angles in the ring agree very well with additive scheme based on angular substituent parameters. X-X electron density maps support the view that the C-N bond does not exhibitπ-character, and, hence, the nitro group interacts with the ring mostly by inductive effects. Plenum Publishing Corporation, 1992 Boese Roland Inst. für Anorg. Chemie, Universität-GH Essen, 4300, Essen, Germany aut Bläser Dieter Inst. für Anorg. Chemie, Universität-GH Essen, 4300, Essen, Germany aut Nussbaumer Michael Inst. für Anorg. Chemie, Universität-GH Essen, 4300, Essen, Germany aut Krygowski Tadeusz Department of Chemistry, University of Warsaw, Pasteura 1, 02093, Warszawa, Poland aut Structural Chemistry Kluwer Academic Publishers 3/5(1992-10-01), 363-368 1040-0400 3:5<363 1992 3 11224 https://doi.org/10.1007/BF00678559 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00678559 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Boese Roland Inst. für Anorg. Chemie, Universität-GH Essen, 4300, Essen, Germany aut NATIONALLICENCE 700 1- Bläser Dieter Inst. für Anorg. Chemie, Universität-GH Essen, 4300, Essen, Germany aut NATIONALLICENCE 700 1- Nussbaumer Michael Inst. für Anorg. Chemie, Universität-GH Essen, 4300, Essen, Germany aut NATIONALLICENCE 700 1- Krygowski Tadeusz Department of Chemistry, University of Warsaw, Pasteura 1, 02093, Warszawa, Poland aut NATIONALLICENCE 773 0- Structural Chemistry Kluwer Academic Publishers 3/5(1992-10-01), 363-368 1040-0400 3:5<363 1992 3 11224 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer