caa a22 4500 46911343X CHVBK 20180323133117.0 cr unu---uuuuu 170328e19920701xx s 000 0 eng 10.1007/BF02037108 doi (NATIONALLICENCE)springer-10.1007/BF02037108 Gas phase chromatography of halides of elements 104 and 105 [Elektronische Daten] [A. Türler, H. Gäggeler, K. Gregorich, H. Barth, W. Brüchle, K. Czerwinski, M. Gober, N. Hannink, R. Henderson, D. Hoffman, D. Jost, C. Kacher, B. Kadkhodayan, J. Kovacs, J. Kratz, S. Kreek, D. Lee, J. Leyba, M. Nurmia, M. Schädel, U. Scherer, Schimpf,, D. Vermeulen, A. Weber, H. Zimmermann, I. Zvara] On-line isothermal gas phase chromatography was used to study halides of261104 (T1/2=65 s) and262,263105 (T1/2=34 s and 27 s) produced an atom-at-a time via the reactions248Cm(18O, 5n) and249Bk(18O, 5n, 4n), respectively. Using HBr and HCl gas as halogenating agents, we were able to produce volatile bromides and chlorides of the above mentioned elements and study their behavior compared to their lighter homologs in Groups 4 or 5 of the periodic table. Element 104 formed more volatile bromide than its homolog Hf. In contrast, element 105 bromides were found to be less volatile than the bromides of the group 5 elements Nb and Ta. Both 104 and Hf chlorides were observed to be more volatile than their respective bromides. Akadémiai Kiadó, 1992 Türler A. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Gäggeler H. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut Gregorich K. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Barth H. Philipps Universität Marburg, D-3550, Marburg, (Germany) aut Brüchle W. GSI, Gesellschaft für Schwerionenforschung mbH, D-61, Darmstadt, (Germany) aut Czerwinski K. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Gober M. Institut für Kernchemie, Universität Mainz, D-6500, Mainz, (Germany) aut Hannink N. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Henderson R. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Hoffman D. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Jost D. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut Kacher C. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Kadkhodayan B. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Kovacs J. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut Kratz J. Institut für Kernchemie, Universität Mainz, D-6500, Mainz, (Germany) aut Kreek S. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Lee D. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Leyba J. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Nurmia M. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut Schädel M. GSI, Gesellschaft für Schwerionenforschung mbH, D-61, Darmstadt, (Germany) aut Scherer U. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut Schimpf, GSI, Gesellschaft für Schwerionenforschung mbH, D-61, Darmstadt, (Germany) aut Vermeulen D. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut Weber A. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut Zimmermann H. Institut für Kernchemie, Universität Mainz, D-6500, Mainz, (Germany) aut Zvara I. JINR, Joint Institute for Nuclear Research, 141980, Dubna, (USSR) aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 160/2(1992-07-01), 327-339 0236-5731 160:2<327 1992 160 10967 https://doi.org/10.1007/BF02037108 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02037108 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Türler A. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Gäggeler H. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut NATIONALLICENCE 700 1- Gregorich K. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Barth H. Philipps Universität Marburg, D-3550, Marburg, (Germany) aut NATIONALLICENCE 700 1- Brüchle W. GSI, Gesellschaft für Schwerionenforschung mbH, D-61, Darmstadt, (Germany) aut NATIONALLICENCE 700 1- Czerwinski K. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Gober M. Institut für Kernchemie, Universität Mainz, D-6500, Mainz, (Germany) aut NATIONALLICENCE 700 1- Hannink N. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Henderson R. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Hoffman D. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Jost D. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut NATIONALLICENCE 700 1- Kacher C. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Kadkhodayan B. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Kovacs J. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut NATIONALLICENCE 700 1- Kratz J. Institut für Kernchemie, Universität Mainz, D-6500, Mainz, (Germany) aut NATIONALLICENCE 700 1- Kreek S. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Lee D. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Leyba J. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Nurmia M. Chemistry Department, University of California, 94720, Berkeley, CA, (USA) aut NATIONALLICENCE 700 1- Schädel M. GSI, Gesellschaft für Schwerionenforschung mbH, D-61, Darmstadt, (Germany) aut NATIONALLICENCE 700 1- Scherer U. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut NATIONALLICENCE 700 1- Schimpf GSI, Gesellschaft für Schwerionenforschung mbH, D-61, Darmstadt, (Germany) aut NATIONALLICENCE 700 1- Vermeulen D. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut NATIONALLICENCE 700 1- Weber A. PSI, Paul Scherrer Institut, CH-5232, Villigen, (Switzerland) aut NATIONALLICENCE 700 1- Zimmermann H. Institut für Kernchemie, Universität Mainz, D-6500, Mainz, (Germany) aut NATIONALLICENCE 700 1- Zvara I. JINR, Joint Institute for Nuclear Research, 141980, Dubna, (USSR) aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 160/2(1992-07-01), 327-339 0236-5731 160:2<327 1992 160 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer