caa a22 4500 46911388X CHVBK 20180323133119.0 cr unu---uuuuu 170328e19921101xx s 000 0 eng 10.1007/BF02163841 doi (NATIONALLICENCE)springer-10.1007/BF02163841 Surface modifications of ferrocene using argon ion implantation and γ-irradiation [Elektronische Daten] [V. Dedgaonkar, N. Chabria, S. Ogale] The effect of Ar+-ion implantation (energy 100 keV) has been studied on ferrocene pellets at 1×1014 and 5×1014 ions/cm2 doses. The characterization techniques used were infrared spectroscopy, small-angle X-ray diffraction and bulk X-ray diffraction. At the lower dose, formation of a metastable alkene occurred; at the higher dose a metastable alkane was formed. The X-ray data showed that metastable phases like Fe−C, (Fe−C)H and carbon phases were produced at the surface. Not being observable on the surface, the organic counterparts are expected to be volatile in nature. When treated with varying energy doses, ferrocene showed bulk damage; the IR spectra showed the loss of fine structure and only a single peak persisted, which was due to metal-ring vibration. Akadémiai Kiadó, 1992 Dedgaonkar V. Department of Chemistry, University of Poona, 411 007, Pune, India aut Chabria N. Department of Chemistry, University of Poona, 411 007, Pune, India aut Ogale S. Department of Physics, University of Poona, 411 007, Pune, India aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 166/4(1992-11-01), 351-357 0236-5731 166:4<351 1992 166 10967 https://doi.org/10.1007/BF02163841 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02163841 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Dedgaonkar V. Department of Chemistry, University of Poona, 411 007, Pune, India aut NATIONALLICENCE 700 1- Chabria N. Department of Chemistry, University of Poona, 411 007, Pune, India aut NATIONALLICENCE 700 1- Ogale S. Department of Physics, University of Poona, 411 007, Pune, India aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 166/4(1992-11-01), 351-357 0236-5731 166:4<351 1992 166 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer