caa a22 4500 469113944 CHVBK 20180323133119.0 cr unu---uuuuu 170328e19921101xx s 000 0 eng 10.1007/BF02167787 doi (NATIONALLICENCE)springer-10.1007/BF02167787 Radiation-induced decomposition of the tributyl phosphate-nitric acid system: Role of nitric acid [Elektronische Daten] [M. Krishnamurthy, R. Sampathkumar] Radiation-induced decomposition of tributyl phosphate-nitric acid as a two-component system has been studied. Degradation products, dibutylphosphoric acid (DBP) and monobutylphosphoric acid (MBP), were determined by separation-extraction method. 0.59, 0.78 and 1.38 are the G (DBP) values and 0.15, 0.17 and 0.13 are the G (MBP) values obtained for pure TBP, TBP-3M HNO3 extract and TBP-5M HNO3 extract, respectively. G (−HNO3) values are 5.19 and 6.15 for 3M HNO3 and 5M HNO3 extracts. It is shown that nitric acid plays a significant role in enhancing the decomposition of TBP. Akadémiai Kiadó, 1992 Krishnamurthy M. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut Sampathkumar R. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 166/5(1992-11-01), 421-429 0236-5731 166:5<421 1992 166 10967 https://doi.org/10.1007/BF02167787 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02167787 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Krishnamurthy M. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut NATIONALLICENCE 700 1- Sampathkumar R. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 166/5(1992-11-01), 421-429 0236-5731 166:5<421 1992 166 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer