caa a22 4500 469114029 CHVBK 20180323133119.0 cr unu---uuuuu 170328e19920901xx s 000 0 eng 10.1007/BF02169575 doi (NATIONALLICENCE)springer-10.1007/BF02169575 Reactions of carbonate radical with cobalt(II) aminopolycarboxylates [Elektronische Daten] [P. Mandal, D. Bardhan, S. Bhattacharyya] Reactions of carbonate (CO 3 −· ) and bicarbonate (HCO 3 · ) radicals generated by photolysis of a carbonate or bicarbonate solution at pH 11.2 and 8.5, respectively, with Co(II) complexes of iminodiacetic acid (IDA) and ethylenediaminetetraacetic acid (EDTA) have been studied. The rate constants for the reactions were in the order of 106-107 dm3mol−1s−1. From the time-resolved spectroscopy of the products formed after reaction of CO 3· −· or HCO 3 · , it is observed that CO 3 −· or HCO 3 · oxidize the metal center to its higher oxidation state. Akadémiai Kiadó, 1992 Mandal P. Nuclear Chemistry Division, Saha Institute of Nuclear Physics, Sector I, Block, AF, Bidhan nagar, 700 064, Calcutta, India aut Bardhan D. Nuclear Chemistry Division, Saha Institute of Nuclear Physics, Sector I, Block, AF, Bidhan nagar, 700 064, Calcutta, India aut Bhattacharyya S. Nuclear Chemistry Division, Saha Institute of Nuclear Physics, Sector I, Block, AF, Bidhan nagar, 700 064, Calcutta, India aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 166/2(1992-09-01), 87-96 0236-5731 166:2<87 1992 166 10967 https://doi.org/10.1007/BF02169575 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02169575 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mandal P. Nuclear Chemistry Division, Saha Institute of Nuclear Physics, Sector I, Block, AF, Bidhan nagar, 700 064, Calcutta, India aut NATIONALLICENCE 700 1- Bardhan D. Nuclear Chemistry Division, Saha Institute of Nuclear Physics, Sector I, Block, AF, Bidhan nagar, 700 064, Calcutta, India aut NATIONALLICENCE 700 1- Bhattacharyya S. Nuclear Chemistry Division, Saha Institute of Nuclear Physics, Sector I, Block, AF, Bidhan nagar, 700 064, Calcutta, India aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 166/2(1992-09-01), 87-96 0236-5731 166:2<87 1992 166 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer