caa a22 4500 469122641 CHVBK 20180323133143.0 cr unu---uuuuu 170328e19920501xx s 000 0 eng 10.1007/BF02368533 doi (NATIONALLICENCE)springer-10.1007/BF02368533 A physical interpretation of Schwan's limit current of linearity [Elektronische Daten] [Eric McAdams, Jacques Jossinet] In this the second of a series of papers on the nonlinearity of the electrode-electrolyte interface impedance, the wealth of experimental observations which exists in the literature on AC impedance nonlinearity is physically interpreted. The interface impedance is well represented by the parallel combination of a constant phase angle impedance and a charge transfer resistance. The charge transfer resistance is the major source of the observed nonlinearities. As a result, the current limit of linearity, i L , increases with frequency such that i L is proportional to ωβ. The series resistance, R s , of the interface impedance initially increases with applied signal amplitude, reaches a maximum and then decreases. The series reactance, X s , decreases monotonically with signal amplitude. Pergamon Press Ltd., 1992 Electrode nationallicence Impedance nationallicence Nonlinearity nationallicence McAdams Eric The Northern Ireland Bio-Engineering Centre, University of Ulster at Jordanstown, Shore Road, Newtonabbey, BT37 0QB, Co Antrim, N. Ireland aut Jossinet Jacques INSERM Unit 281, 151 Cours Albert Thomas, 69424, Lyon, Cedex 03, France aut Annals of Biomedical Engineering Kluwer Academic Publishers 20/3(1992-05-01), 307-319 0090-6964 20:3<307 1992 20 10439 https://doi.org/10.1007/BF02368533 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02368533 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- McAdams Eric The Northern Ireland Bio-Engineering Centre, University of Ulster at Jordanstown, Shore Road, Newtonabbey, BT37 0QB, Co Antrim, N. Ireland aut NATIONALLICENCE 700 1- Jossinet Jacques INSERM Unit 281, 151 Cours Albert Thomas, 69424, Lyon, Cedex 03, France aut NATIONALLICENCE 773 0- Annals of Biomedical Engineering Kluwer Academic Publishers 20/3(1992-05-01), 307-319 0090-6964 20:3<307 1992 20 10439 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 469122641 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer