caa a22 4500 469129905 CHVBK 20180323133201.0 cr unu---uuuuu 170328e19920901xx s 000 0 eng 10.1007/BF00324834 doi (NATIONALLICENCE)springer-10.1007/BF00324834 Correction parameters in X-ray fluorescence analysis applying the limit dilution method (LDM) [Elektronische Daten] I. Correction of the diluent effect and optimization of the selection of standards [F. Bosch Reig, V. Peris Martinez, F. Bosch Mossi, J. Gimeno Adelantado] Summary: Some corrective parameters: H, M, Y and Y/H are defined from the mathematical development justifying the Limit Dilution Method (LDM) in XRF analysis. These corrective parameters, for a given diluent and dilution, are characteristic of the analyte in each sample. The influence of these parameters on important phenomena such as the diluent effect is evaluated by a theoretical model. Using parameters Y, an algorithm is proposed which corrects the diluent effect and establishes linear functions of fluorescence intensity vs. analyte concentration. This paper also proposes a selection procedure for the optimum standard for a given problem using the Y/H parameter. The method is applied to the XRF analysis of mixtures of iron and zirconium oxides and these results show the corrective action of the suggested parameters and the appropriateness of the selection of the standards. Springer-Verlag, 1992 Bosch Reig F. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut Peris Martinez V. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut Bosch Mossi F. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut Gimeno Adelantado J. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut Fresenius' Journal of Analytical Chemistry Springer-Verlag 344/1-2(1992-09-01), 16-21 0937-0633 344:1-2<16 1992 344 216 https://doi.org/10.1007/BF00324834 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00324834 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bosch Reig F. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut NATIONALLICENCE 700 1- Peris Martinez V. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut NATIONALLICENCE 700 1- Bosch Mossi F. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut NATIONALLICENCE 700 1- Gimeno Adelantado J. Department of Analytical Chemistry, Faculty of Chemistry, University of Valencia, E-46100, Burjassot, Valencia, Spain aut NATIONALLICENCE 773 0- Fresenius' Journal of Analytical Chemistry Springer-Verlag 344/1-2(1992-09-01), 16-21 0937-0633 344:1-2<16 1992 344 216 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 469129875 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer