caa a22 4500 475758498 CHVBK 20180406123543.0 cr unu---uuuuu 170329e20000101xx s 000 0 eng 10.1007/BF02499065 doi (NATIONALLICENCE)springer-10.1007/BF02499065 Electrochemical methylation of a chelate anionic NiI complex with methylcobaloxime. Partial modeling of the action mechanism of the active center of acetyl-CoA synthase [Elektronische Daten] [R. Rakhimov, K. Butin] Electrochemically generated anions of Co and Ni chelate complexes can be alkylated with BunBr, BunI, and (dmgH)2CoMe (dmgH is the dimethylglyoximate anion). Unlike the anionic Co complexes, the anionic Ni complex cannot be alkylated with BunBr; however, it reacts with stronger alkylating agents (BunI and (dmgH)2CoMe). It is assumed that the electrochemical alkylation of the Ni complex with (dmgH)2CoMe can serve as a model for alkylation occurring in biological synthesis of acetyl coenzyme A. Reactions of some Co chelate anions with BunI can proceedvia the reduction of the latter. Kluwer Academic/Plenum Publishers, 2000 cobalt nationallicence nickel nationallicence chelate complexes nationallicence alkylation nationallicence methylcobaloxime nationallicence bioinorganic enzymology nationallicence Rakhimov R. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Butin K. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/1(2000-01-01), 56-59 1066-5285 49:1<56 2000 49 11172 https://doi.org/10.1007/BF02499065 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02499065 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Rakhimov R. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Butin K. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/1(2000-01-01), 56-59 1066-5285 49:1<56 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer