caa a22 4500 475758668 CHVBK 20180406123544.0 cr unu---uuuuu 170329e20000101xx s 000 0 eng 10.1007/BF02499082 doi (NATIONALLICENCE)springer-10.1007/BF02499082 Metallation of the methyl group in o -nitrosotoluene: synthesis and the molecular structure of the binuclear complex [ o -(NO)(CH2)C6H4)]2Pd2(μ-OOCCF3)2 [Elektronische Daten] [T. Stromnova, S. Orlova, D. Kazyul'kin, I. Stolyarov, I. Eremenko] The reaction of the tetranuclear cluster Pd4(CO)4(OOCCF3)4 witho-nitrosotoluene afforded the Pd11-containing complex [o-(NO)(CH2)C6H4]2Pd2(μ-OOCCF3)2. The elimination of CO2 and the formation of organic products of transformation of tolylnitrene species (azotoluene, ditolylamine, and tolylisocyanate) were observed in the course of the reaction. The title complex was characterized by IR and1H NMR spectroscopy. Its structure was established by X-ray diffraction analysis. It was suggested that the reaction proceeds through intermediate formation of nitrene complexes. Kluwer Academic/Plenum Publishers, 2000 palladium nationallicence carbonyl complexes nationallicence clusters nationallicence metallation nationallicence nitrosotoluene nationallicence Stromnova T. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Orlova S. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Kazyul'kin D. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Stolyarov I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/1(2000-01-01), 150-153 1066-5285 49:1<150 2000 49 11172 https://doi.org/10.1007/BF02499082 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02499082 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Stromnova T. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Orlova S. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Kazyul'kin D. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Stolyarov I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/1(2000-01-01), 150-153 1066-5285 49:1<150 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer