caa a22 4500 475758722 CHVBK 20180406123544.0 cr unu---uuuuu 170329e20000101xx s 000 0 eng 10.1007/BF02499071 doi (NATIONALLICENCE)springer-10.1007/BF02499071 Diastereoselective synthesis of polyfunctional compounds based on the tandem sequence of three Ad E reactions using cyclic vinyl ethers as first alkene components [Elektronische Daten] [M. Lazareva, Yu. Kryschenko, R. Caple, W. Smit, K. Lyssenko, A. Shashkov] The reaction of the bicyclic thiophanium ions salts, generated by the sequential interaction ofp-TolSCI with dihydropyran or 1-methoxycycloalkene and then with an acyclic alkyl vinyl ether in the presence of a Lewis acid and with silicon- or tin-capped π-donors, proceeds with high diastereoselectivity at all newly created chiral centers. Kluwer Academic/Plenum Publishers, 2000 arenesulfenyl chloride nationallicence dihydropyran nationallicence 1-methoxycycloalkenes nationallicence electrophilic addition reaction nationallicence episulfonium ion nationallicence bicyclic thiophanium ion nationallicence silicon- and tin-capped π-donors nationallicence stereoselective ring opening nationallicence Lazareva M. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Kryschenko Yu N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Caple R. Chemistry Department, University of Minnesota-Duluth, 10 University Drive, 55812, Duluth, MN, USA aut Smit W. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Lyssenko K. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Shashkov A. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/1(2000-01-01), 85-97 1066-5285 49:1<85 2000 49 11172 https://doi.org/10.1007/BF02499071 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02499071 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lazareva M. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Kryschenko Yu N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Caple R. Chemistry Department, University of Minnesota-Duluth, 10 University Drive, 55812, Duluth, MN, USA aut NATIONALLICENCE 700 1- Smit W. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Lyssenko K. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Shashkov A. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/1(2000-01-01), 85-97 1066-5285 49:1<85 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer