caa a22 4500 475758773 CHVBK 20180406123544.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1007/BF02494884 doi (NATIONALLICENCE)springer-10.1007/BF02494884 Nonideality of binary mixtures in the adsorbent micropores [Elektronische Daten] [E. Ustinov, N. Polyakov] Analysis of a binary equilibrium in a distinct micropore showed that the noouniformity of the adsorption field results in a negative deviation of the adsorption solution from ideal behavior. This deviation is due to a decrease in the entropy and internal energy caused by rearrangement of adsorbed molecules. Different interactions between identical and different molecules in distinct micropores also result in a negative deviation from ideal behavior. A criterion was formulated that allows one to elucidate how the deviation from ideality depends on the nonuniformity of the adsorption space and the character of the interaction between molecules in a micropore. Kluwer Academic/Plenum Publishers, 2000 adsorption equilibrium nationallicence binary systems nationallicence micropores nationallicence nonideality nationallicence adsorption solutions nationallicence Ustinov E. St. Petersburg State Technological Institute (Technical University), 26 Moskovskii prosp., 198013, St. Petersburg, Russian Federation aut Polyakov N. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1006-1011 1066-5285 49:6<1006 2000 49 11172 https://doi.org/10.1007/BF02494884 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494884 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ustinov E. St. Petersburg State Technological Institute (Technical University), 26 Moskovskii prosp., 198013, St. Petersburg, Russian Federation aut NATIONALLICENCE 700 1- Polyakov N. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1006-1011 1066-5285 49:6<1006 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer