caa a22 4500 475758803 CHVBK 20180406123544.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1007/BF02494896 doi (NATIONALLICENCE)springer-10.1007/BF02494896 Aqueous solution of N -methylmorpholine N -oxide as a stationary liquid phase in steam chromatography [Elektronische Daten] [V. Berezkin, E. Sorokina, A. Sokolov, A. Arzamastsev, L. Golova] The retention of more than 70 voltatile organic compounds of different classes was studied by steam chromatography using aqueous solutions ofN-methylmorpholineN-oxide as the stationary liquid phase (SLP). The effects of temperature and composition of the mobile phase on the retention factors (k) for polar and nonpolar sorbates were elucidated. An unusual order of elution of aliphatic alcohols was noted, namely,tert-butyl alcohol <sec-butyl alcohol < isopentyl alcohol <isobutyl alcohol<isopropyl alcohol <n-pentyl alcohol <n-butyl alcohol <n-propyl alcohol <ethanol <methanol. The retention of cyclohexanol was longer than those of benzyl alcohol andn-hexyl alcohol. Nitrogen-containing compounds were selectively separated on the water-organic SLP studied. For example, the retention of aniline was much longer than those of its derivatives,N,N-dimethylaniline andN,N-diethylaniline, having higher boiling points. Kluwer Academic/Plenum Publishers, 2000 steam chromatography nationallicence selective stationary liquid phase nationallicence N -methylmorpholine oxide nationallicence retention factor nationallicence separation of alcohols, amines, and monoterpenes nationallicence Berezkin V. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 117912, Moscow, Russian Federation aut Sorokina E. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 117912, Moscow, Russian Federation aut Sokolov A. I. M. Sechenov Moscow Medical Academy, 13 Nikitsky bulvar, 121019, Moscow, Russian Federation aut Arzamastsev A. I. M. Sechenov Moscow Medical Academy, 13 Nikitsky bulvar, 121019, Moscow, Russian Federation aut Golova L. State Enterprise "Russian Research and Development Institute of Polymer Fibers”, 5 ul. Kolontseva, 141009, Mytishi, Moscow Region, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1071-1078 1066-5285 49:6<1071 2000 49 11172 https://doi.org/10.1007/BF02494896 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494896 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Berezkin V. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Sorokina E. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Sokolov A. I. M. Sechenov Moscow Medical Academy, 13 Nikitsky bulvar, 121019, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Arzamastsev A. I. M. Sechenov Moscow Medical Academy, 13 Nikitsky bulvar, 121019, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Golova L. State Enterprise "Russian Research and Development Institute of Polymer Fibers”, 5 ul. Kolontseva, 141009, Mytishi, Moscow Region, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1071-1078 1066-5285 49:6<1071 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer