caa a22 4500 475758854 CHVBK 20180406123544.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1007/BF02494895 doi (NATIONALLICENCE)springer-10.1007/BF02494895 The structure of benzoyldimedone from X-ray diffraction analysis [Elektronische Daten] [E. Borisov, A. Verenich, A. Govorova, A. Lyakhov, T. Khlebnikova] The structure of benzoyldimedone was established by X-ray diffraction analysis. The only tautomer was found. In this tautomer, the enol proton is covalently bound to the oxygen atom that is remote from the phenyl group. The role of steric and electronic factors in stabilization of the enol structure is analyzed. The geometric characteristics of the ring formed through an intramolecular hydrogen bond are discussed. Kluwer Academic/Plenum Publishers, 2000 X-ray diffraction analysis nationallicence tautomerism nationallicence intramolecular hydrogen bond nationallicence β-diketones nationallicence β-triketones nationallicence conjugation nationallicence 2-benzoyl-5,5-dimethylcyclohexane-1,3-dione nationallicence Borisov E. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut Verenich A. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut Govorova A. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut Lyakhov A. Institute of Physicochemical Problems, Belarussian State University, 14 ul. Leningradskaya, 220080, Minsk, Belarus aut Khlebnikova T. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1068-1070 1066-5285 49:6<1068 2000 49 11172 https://doi.org/10.1007/BF02494895 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494895 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Borisov E. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut NATIONALLICENCE 700 1- Verenich A. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut NATIONALLICENCE 700 1- Govorova A. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut NATIONALLICENCE 700 1- Lyakhov A. Institute of Physicochemical Problems, Belarussian State University, 14 ul. Leningradskaya, 220080, Minsk, Belarus aut NATIONALLICENCE 700 1- Khlebnikova T. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1068-1070 1066-5285 49:6<1068 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer