caa a22 4500 475758919 CHVBK 20180406123544.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1007/BF02494891 doi (NATIONALLICENCE)springer-10.1007/BF02494891 Electrochemical potentials, optical transitions, and frontier orbitals of non-bridged and bridged bent sandwich zirconocene complexes [Elektronische Daten] [G. Loukova, V. Strelets] A linear correlation between the electrochemical gap values (G=E ox−E red) and the energies of optical transition in the UV-vis region was found and justified for a series of non-bridged and bridged bent-sandwich zirconocene complexes with the general formula R(η5-L)2ZrX2, where L=cyclopentadienyl (Cp), indenyl (Ind), fluorenyl (Flu); X=Cl, Me; the bridging group R=SiMe2, (CH2)2. Kluwer Academic/Plenum Publishers, 2000 metallocene complexes, ansa - and bent sandwich dichloride and dimethyl zirconocenes nationallicence frontier molecular orbitals, redox properties, electrochemical gap, cyclic voltammetry nationallicence electron transitions, electronic spectra, correlations nationallicence Loukova G. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Strelets V. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1037-1039 1066-5285 49:6<1037 2000 49 11172 https://doi.org/10.1007/BF02494891 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494891 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Loukova G. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Strelets V. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1037-1039 1066-5285 49:6<1037 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer