caa a22 4500 475758986 CHVBK 20180406123545.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1007/BF02494906 doi (NATIONALLICENCE)springer-10.1007/BF02494906 Ruthenium phosphine complexes as catalysts of alternating copolymerization of ethylene and carbon monoxide [Elektronische Daten] [O. Gusev, A. Kal'sin, T. Peganova, P. Petrovskii, G. Belov, E. Novikova] The properties of the ruthenium (II) phosphine complexes [Ru(dppe)2(OTs)2] and [Ru{PhP(CH2CH2CH2PPh2)2}(OTs)2] as catalysts of alternating copolymerization of ethylene and carbon monoxide were studied. The catalytic activity of these complexes in the absence of cocatalysis is low, but it is substantially increased in the presence of trifluoroacetic acid or 1,4-benzoquinone. These compounds are the first ruthenium complexes which catalyze copolymerization of ethylene and CO. Kluwer Academic/Plenum Publishers, 2000 ruthenium complex nationallicence copolymerization nationallicence ethylene nationallicence carbon monoxide nationallicence Gusev O. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Kal'sin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Peganova T. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Belov G. Institute of Problems of Chemical Physics, 142432, Chernogolovka, Moscow Region, Russian Federation aut Novikova E. Institute of Problems of Chemical Physics, 142432, Chernogolovka, Moscow Region, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1113-1115 1066-5285 49:6<1113 2000 49 11172 https://doi.org/10.1007/BF02494906 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494906 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gusev O. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Kal'sin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Peganova T. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Belov G. Institute of Problems of Chemical Physics, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Novikova E. Institute of Problems of Chemical Physics, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 1113-1115 1066-5285 49:6<1113 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer