caa a22 4500 47575901X CHVBK 20180406123545.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1007/BF02494882 doi (NATIONALLICENCE)springer-10.1007/BF02494882 Electronic absorption spectra of charge-transfer complexes and effects of substituents in radical cations [Elektronische Daten] [A. Egorochkin, O. Zderenova, S. Skobeleva] The effects of X substituents on the energies of charge-transfer bandshv CT in electronic absorption spectra of charge-transfer complexes of π-, n-, or σ-donors (DX) with π- or σ-acceptors (A) as well as on the ionization potentialsI D of individual DX molecules are described by the equationhv CT(l D)=a +bσ1 +cσ R + +dσα. When DX and A are fixed, the inductive (bσ1), resonance (cσ R + ), and polarization (dσα) contributions tohv CT andI D are virtually identical. The electronic structure of the D.+X donor component of the compact [A.−, D.+X] radical-ionic pair in a solution is similar to that of the radical cation generated upon photoionization of the individual DX molecule in the gaseous phase. Kluwer Academic/Plenum Publishers, 2000 charge-transfer complexes nationallicence ionization potentials nationallicence radical cations nationallicence inductive effect nationallicence conjugation nationallicence polarizability of substituents nationallicence Egorochkin A. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhni Novgorod, Russian Federation aut Zderenova O. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhni Novgorod, Russian Federation aut Skobeleva S. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhni Novgorod, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 997-1001 1066-5285 49:6<997 2000 49 11172 https://doi.org/10.1007/BF02494882 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494882 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Egorochkin A. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhni Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Zderenova O. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhni Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Skobeleva S. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhni Novgorod, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/6(2000-06-01), 997-1001 1066-5285 49:6<997 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer