caa a22 4500 475759192 CHVBK 20180406123545.0 cr unu---uuuuu 170329e20000901xx s 000 0 eng 10.1007/BF02495157 doi (NATIONALLICENCE)springer-10.1007/BF02495157 A spectral study of the interaction of dioxygen with sublimed layers of manganese(ii) meso -tetraphenylporphyrinate [Elektronische Daten] [T. Kurtikyan, T. Stepanyan, G. Martirosyan, R. Kazaryan, V. Madakyan] The low-temperature interaction of sublimed layers of manganese(ii)meso-tetraphenylporphyrinate (MnTPP) with O2, which has previously been observed only in solutions and in an inert gas matrix, was found by electron absorption and IR spectroscopy. The coordination of O2 with sublimed MnTPP layers is only partially reversible. Bands that can serve as IR-spectral markers characteristic of the high-spin MnII ion in MnTPP and its axial complexes were observed. Kluwer Academic/Plenum Publishers, 2000 manganese(ii) meso -tetraphenylporphyrinate nationallicence sublimed layers nationallicence dioxygen coordination nationallicence electron absorption spectroscopy nationallicence IR spectroscopy nationallicence Kurtikyan T. Armenian Research Institute of Applied Chemistry, 70 prosp. Bagratunyats, 375005, Yerevan, Republic of Armenia aut Stepanyan T. Molecule Structure Research Center of National Academy of Sciences of Republic of Armenia, 26 prosp. Azatutyan, 375014, Yerevan, Republic of Armenia aut Martirosyan G. Armenian Research Institute of Applied Chemistry, 70 prosp. Bagratunyats, 375005, Yerevan, Republic of Armenia aut Kazaryan R. M. Geratsi Medical State University, 375025, Yerevan, Republic of Armenia aut Madakyan V. M. Geratsi Medical State University, 375025, Yerevan, Republic of Armenia aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/9(2000-09-01), 1540-1543 1066-5285 49:9<1540 2000 49 11172 https://doi.org/10.1007/BF02495157 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495157 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kurtikyan T. Armenian Research Institute of Applied Chemistry, 70 prosp. Bagratunyats, 375005, Yerevan, Republic of Armenia aut NATIONALLICENCE 700 1- Stepanyan T. Molecule Structure Research Center of National Academy of Sciences of Republic of Armenia, 26 prosp. Azatutyan, 375014, Yerevan, Republic of Armenia aut NATIONALLICENCE 700 1- Martirosyan G. Armenian Research Institute of Applied Chemistry, 70 prosp. Bagratunyats, 375005, Yerevan, Republic of Armenia aut NATIONALLICENCE 700 1- Kazaryan R. M. Geratsi Medical State University, 375025, Yerevan, Republic of Armenia aut NATIONALLICENCE 700 1- Madakyan V. M. Geratsi Medical State University, 375025, Yerevan, Republic of Armenia aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/9(2000-09-01), 1540-1543 1066-5285 49:9<1540 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer