caa a22 4500 47575946X CHVBK 20180406123546.0 cr unu---uuuuu 170329e20000901xx s 000 0 eng 10.1007/BF02495167 doi (NATIONALLICENCE)springer-10.1007/BF02495167 Reaction of Ru3(CO)12 with 1,3-diferrocenylprop-2-ene-1-one. Crystal and molecular structures of the complexes Ru3(CO)8(FcC=CHCOFc)2 and [Ru(CO)2Cl(FcC=CHCOFc)]2 [Elektronische Daten] [S. Osintseva, E. Petrovskaya, L. Rybin, A. Kreindlin, F. Dolgushin, A. Yanovsky, P. Petrovskii, M. Rybinskaya] The reaction of Ru3(CO)12 with 1,3-diferrocenylprop-2-en-1-one,trans-FcCH=CHCOFc (where Fc is ferrocenyl), in boiling hexane afforded the complex (2c), which was converted into (3c) upon further heating. These complexes gave the complex (4) containing two Cl-bridged oxaruthenacycles upon dissolution in CHCl3 or CH2Cl2. The structures of complexes 3 and 4 were established by X-ray diffraction analysis. According to the data of1H NMR spectroscopy, the Cl-bridged complex exists in solutions as a mixture of isomers along with the monomeric form resulting from the cleavage of the halide bridges. All interconversions of the isomers occur with the participation of the monomeric form. Kluwer Academic/Plenum Publishers, 2000 dodecacarbonyltriruthenium nationallicence 1,3-diferrocenylprop-2-en-1-one nationallicence oxaruthenapentadienyl rings nationallicence halogen-bridged complexes nationallicence dimeric and monomeric structures nationallicence X-ray diffraction analysis nationallicence IR spectra nationallicence NMR spectra nationallicence Osintseva S. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Petrovskaya E. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Rybin L. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Kreindlin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Dolgushin F. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Yanovsky A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Rybinskaya M. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/9(2000-09-01), 1605-1612 1066-5285 49:9<1605 2000 49 11172 https://doi.org/10.1007/BF02495167 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495167 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Osintseva S. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Petrovskaya E. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Rybin L. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Kreindlin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Dolgushin F. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Yanovsky A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Rybinskaya M. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/9(2000-09-01), 1605-1612 1066-5285 49:9<1605 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer