caa a22 4500 475759524 CHVBK 20180406123546.0 cr unu---uuuuu 170329e20000701xx s 000 0 eng 10.1007/BF02495782 doi (NATIONALLICENCE)springer-10.1007/BF02495782 Absolute configuration and anti-hypercholesterolemic activity of (+)- and (−)-4-(2,6-dimethylheptyl)benzoic acids [Elektronische Daten] [G. Gamalevich, A. Vlasyuk, V. Voblikova, E. Serebryakov] The biologically inactive (+)-enantiomer of 4-(2,6-dimethylheptyl)benzoic acid was converted into the known (R)-3,7-dimethyloctanol withee≥96% by ozonolysis followed by a two-step reduction of the ozonide. This confirmed theR configuration of the starting acid, theS configuration of its biologically active levorotatory antipode, and the absolute configurations assigned to their synthetic precursors. Kluwer Academic/Plenum Publishers, 2000 ( R )-4-(2,6-dimethylheptyl)benzoic acid nationallicence ozonolysis nationallicence stereochemical correlation nationallicence anti-hypercholesterolemic activity nationallicence Gamalevich G. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Vlasyuk A. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Voblikova V. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Serebryakov E. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/7(2000-07-01), 1313-1315 1066-5285 49:7<1313 2000 49 11172 https://doi.org/10.1007/BF02495782 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495782 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gamalevich G. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Vlasyuk A. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Voblikova V. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Serebryakov E. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/7(2000-07-01), 1313-1315 1066-5285 49:7<1313 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer