caa a22 4500 475759540 CHVBK 20180406123546.0 cr unu---uuuuu 170329e20000701xx s 000 0 eng 10.1007/BF02495773 doi (NATIONALLICENCE)springer-10.1007/BF02495773 Synthesis and some properties of lanthanum, neodymium, and samarium tert -butoxycuprates [(ButO)5Cu2Ln]2 [Elektronische Daten] [A. Nikitinsky, L. Bochkarev, S. Khorshev] Lanthanum, neodymium, and samariumtert-butoxycuprates [(ButO)5Cu2Ln]2 were synthesized in high yields by reactions of ButOCu with lanthanide metals, the halides Sml2 and LnX3 (Ln=La, Nd: X=Cl, 1) and by the reaction of ButOLi with a mixture of LnCl3 and CuCl. X-Ray diffraction analysis showed that the structure of [(ButO)5Cu2Sm]2 is based on octahedra formed by four copper atoms in equatorial positions and two samarium atoms in axoal positions; the copper and samarium atoms are linked by μ3-bridging ButO groups. The reactions of lanthanumtert-butoxycuprate with H2O, HCl, CpH, PhC≡CH, and CO2 were studied. Kluwer Academic/Plenum Publishers, 2000 lanthanides nationallicence alkoxycuprates nationallicence synthetic methods nationallicence structure nationallicence reactivity nationallicence Nikitinsky A. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut Bochkarev L. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut Khorshev S. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/7(2000-07-01), 1270-1274 1066-5285 49:7<1270 2000 49 11172 https://doi.org/10.1007/BF02495773 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495773 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Nikitinsky A. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Bochkarev L. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Khorshev S. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/7(2000-07-01), 1270-1274 1066-5285 49:7<1270 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer