caa a22 4500 475759737 CHVBK 20180406123547.0 cr unu---uuuuu 170329e20000701xx s 000 0 eng 10.1007/BF02495758 doi (NATIONALLICENCE)springer-10.1007/BF02495758 The radical cation of hydrogen sulfide and related organic reactions [Elektronische Daten] [N. Berberova, E. Shinkar'] The electrochemical and chemical oxidation (by hinderedo-benzoquinones or NOClO4) of H2S in nonaqueous solutions (MeCN) proceeds with the donation of one electron. The formation of the unstable radical cation of hydrogen sulfide was detected by cyclic voltammetry. The radical cation decomposes to form H+ and the HS. radical. The generation of the hydrogen sulfide radical cation was confirmed by ESR spectroscopy in a frozen Freon matrix. The possibility of using the hydrogen sulfide radical cation in the synthesis of organosulfur compounds under mild conditions was studied. Kluwer Academic/Plenum Publishers, 2000 radical cation of hydrogen sulfide nationallicence oxidative activation nationallicence cyclic voltammetry nationallicence ESR spectroscopy nationallicence reaction mechanism nationallicence Berberova N. Astrakhan State Technical University, 16 ul. Tatishcheva, 414025, Astrakhan, Russian Federation aut Shinkar' E. Astrakhan State Technical University, 16 ul. Tatishcheva, 414025, Astrakhan, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/7(2000-07-01), 1178-1184 1066-5285 49:7<1178 2000 49 11172 https://doi.org/10.1007/BF02495758 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495758 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Berberova N. Astrakhan State Technical University, 16 ul. Tatishcheva, 414025, Astrakhan, Russian Federation aut NATIONALLICENCE 700 1- Shinkar' E. Astrakhan State Technical University, 16 ul. Tatishcheva, 414025, Astrakhan, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/7(2000-07-01), 1178-1184 1066-5285 49:7<1178 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer