caa a22 4500 475759834 CHVBK 20180406123547.0 cr unu---uuuuu 170329e20001201xx s 000 0 eng 10.1023/A:1009540429278 doi (NATIONALLICENCE)springer-10.1023/A:1009540429278 Synthesis of Dolichyl Phosphates with a Fluorescent Label in the gamma-Isoprene Unit of the Chain [Elektronische Daten] [N. Grigorieva, O. Pinsker, S. Mal'tsev, L. Danilov, V. Shibaev, M. Jedrzejas] Stereoselective synthesis of the dolichyl phosphate derivatives WT3C2S-OP and WT2C6,7S-OP* containing the 1-naphtylamino group in the gamma-isoprene unit of the chain was performed. The synthetic scheme includes directed aldol condensation to construct (E)-alfa,beta-disubstituted acroleins, their reductive amination with 1-aminonaphthalene, and phosphorylation of the resulting amino alcohols. Plenum Publishing Corporation, 2000 dolichyl phosphates nationallicence stereodirected aldol condensation nationallicence reductive amination of alfa,beta-disubstituted acroleins nationallicence phosphorylation nationallicence fluorescent label nationallicence Grigorieva N. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Pinsker O. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Mal'tsev S. Department of Microbiology, The University of Alabama at Birmingham, Alabama, 35294, Birmingham, USA aut Danilov L. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Shibaev V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Jedrzejas M. Department of Microbiology, The University of Alabama at Birmingham, Alabama, 35294, Birmingham, USA aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 2065-2071 1066-5285 49:12<2065 2000 49 11172 https://doi.org/10.1023/A:1009540429278 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009540429278 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Grigorieva N. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Pinsker O. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Mal'tsev S. Department of Microbiology, The University of Alabama at Birmingham, Alabama, 35294, Birmingham, USA aut NATIONALLICENCE 700 1- Danilov L. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Shibaev V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Jedrzejas M. Department of Microbiology, The University of Alabama at Birmingham, Alabama, 35294, Birmingham, USA aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 2065-2071 1066-5285 49:12<2065 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer