caa a22 4500 475759915 CHVBK 20180406123547.0 cr unu---uuuuu 170329e20001201xx s 000 0 eng 10.1023/A:1009503421101 doi (NATIONALLICENCE)springer-10.1023/A:1009503421101 Bel'skii V. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Isokinetic relationships for nucleophilic substitution at the saturated carbon atom. Reactions with anions in the gas phase and various solvents [Elektronische Daten] [V. Bel'skii] Isokinetic relationship (IKR) with the parameters T iso = 6103 K and logk iso = 10.402 is applicable to the rate constants for 165 reactions of nucleophilic substitution at the saturated carbon atom involving anionic nucleophiles in proton-donor and polar aprotic solvents and their mixtures. For analogous reactions in the gas phase proceeding via a specific mechanism, IKR is obtained with the parameters T iso = 1505 K and logk iso = 9.972, which is applicable to the reactions occurring under various pressures of an inert gas. Plenum Publishing Corporation, 2000 nucleophilic substitution nationallicence anionic nucleophiles nationallicence rate constants nationallicence isokinetic relationship nationallicence activation parameters nationallicence influence of solvents nationallicence reactions in the gas phase nationallicence Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 1968-1973 1066-5285 49:12<1968 2000 49 11172 https://doi.org/10.1023/A:1009503421101 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009503421101 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Bel'skii V. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 1968-1973 1066-5285 49:12<1968 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 475759915 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer